N-1,2-dimethylbutyl-N'-phenyl-p-phenylenediamine | 101303-18-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-1,2-dimethylbutyl-N'-phenyl-p-phenylenediamine
• 英文别名: 4-N-(3-methylpentan-2-yl)-1-N-phenylbenzene-1,4-diamine
• CAS: 101303-18-8
• 化学式: C₁₈H₂₄N₂
• 分子量: 268.402
• InChiKey: CKFBRICNPWHREC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Direct alkylation of N-alkyl-N'-phenyl-p-phenylenediamine
  申请人：Wang Jin-Yun

  公开号：US20070173668A1

  公开（公告）日：2007-07-26

  A single-step process is disclosed for the ring alkylation of at least one N-alkyl-N′-phenyl-phenylenediamine with at least one olefin wherein the process comprises heating a mixture of the N-alkyl-N′-phenyl-phenylenediamine(s) and olefin(s) in the presence of a catalytic amount of at least one alkyl aluminum halide at a temperature of from about 50 to about 350° C. in a sealed vessel for from about one to about 30 hours.

  揭示了一种单步过程，用于将至少一种N-烷基-N'-苯基-苯二胺与至少一种烯烃进行环烷化反应，其中该过程包括在密封容器中，在存在至少一种烷基铝卤化物的催化剂作用下，将N-烷基-N'-苯基-苯二胺(s)和烯烃(s)的混合物加热至约50℃至约350℃的温度，反应时间为约1至约30小时。
• Preparation of N-substituted-N'-phenyl-P-phenylenediamines
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0617004A1

  公开（公告）日：1994-09-28

  The present invention relates to a process for the preparation of a N-substituted-N'-phenyl-p-phenylenediamine of the formula: comprising reacting (a) a mixture of (1) N-phenyl-p-quinoneimine of the formula: and (2) p-hydroxydiphenylamine in a mole ratio of N-phenyl-p-quinoneimine to p-hydroxydiphenylamine of from 1.5:1 to 1:1.5 with (b) a primary amine of the formula:         R¹-NH₂ in the presence of methanol wherein R¹ is selected from the group of radicals consisting of alkyls having 1 to 20 carbon atoms, cycloalkyls having 6 to 8 carbon atoms and radicals of the structural formula: wherein R² may be the same or different and is independently selected from the group of radicals consisting of hydrogen and an alkyl having 1 carbon atom, R³ is selected from the group of radicals consisting of an alkyl having 1 to 12 carbon atoms and n is an integer of from 0 to 6.

  本发明涉及一种制备式为 N-取代-N'-苯基-对苯二胺的工艺： 包括使(a)式中的(1)N-苯基-对醌亚胺的混合物与(2)式中的(3)N-苯基-对醌亚胺反应： 和(2)对羟基二苯胺（N-苯基对醌亚胺与对羟基二苯胺的摩尔比为 1.5:1 至 1:1.5）与(b)式中的伯胺的混合物反应： R¹-NH₂ 在甲醇存在下，其中 R¹ 选自由具有 1 至 20 个碳原子的烷基、具有 6 至 8 个碳原子的环烷基和结构式如下的基团组成的基团组： 其中 R² 可以相同或不同，且独立地选自氢和具有 1 个碳原子的烷基组成的基团组，R³ 选自具有 1 至 12 个碳原子的烷基组成的基团组，n 为 0 至 6 的整数。
• Rubber composition
  申请人：SUMITOMO RUBBER INDUSTRIES, LTD.

  公开号：EP0819732A2

  公开（公告）日：1998-01-21

  A rubber composition obtained by (a) mixing at least one low air permeable rubber having a vulcanisable functional group and a curing agent, which can vulcanise the low air permeable rubber having the vulcanisable functional group, at a temperature within a range where the low air permeable rubber having vulcanisable functional group is not vulcanised, and (b) blending 25 to 100 parts by weight of at least one rubber having a vulcanisable carbon-carbon double bond per 100 parts by weight of the low air permeable rubber having the vulcanisable functional group with the mixed product, mixing at a temperature within a range where the low air permeable rubber having vulcanisable functional group can be vulcanised to selectively vulcanise the low air permeable rubber having vulcanisable functional group. The rubber composition of the present invention is superior in adhesion property by vulcanisation to other diene rubber compositions and, from the rubber composition, the rubber moulded article not inferior in low air permeability can be obtained.

  通过以下方法获得的橡胶组合物 (a) 在具有可硫化官能团的低透气性橡胶未硫化的温度范围内，混合至少一种 具有可硫化官能团的低透气性橡胶和一种可硫化具有可硫化官能团的低透 气性橡胶的硫化剂，以及 (b) 以每 100 份具有可硫化功能基团的低透气性橡胶的重量计，将 25 至 100 份至少一种具有可硫化碳碳双键的橡胶与混合产品混合，在具有可硫化功能基团的低透气性橡胶可被硫化的温度范围内进行混合，以选择性地硫化具有可硫化功能基团的低透气性橡胶。 与其他二烯橡胶组合物相比，本发明的橡胶组合物在硫化粘合性能方面更优越，并且可以从该橡胶组合物中获得低透气性不差的橡胶模制品。
• Adhesion-promoting system for rubber goods
  申请人：Cytec Surface Specialties Germany GmbH & Co. KG

  公开号：EP2253649A1

  公开（公告）日：2010-11-24

  The invention relates a mixture of a urethane-aldehyde resin UA prepared by condensation of an aldehyde A1 and an alkyl urethane U, and of a novolak PA, to a process for the preparation of the said mixture, and a method of use thereof as adhesion promoter in rubber goods.

  本发明涉及一种由醛 A1 和烷基氨基甲酸酯 U 缩合制备的氨基甲酸酯-醛树脂 UA 与酚醛树脂 PA 的混合物，还涉及制备上述混合物的工艺以及将其用作橡胶制品增粘剂的方法。
• Preparation of a N-substituted phenylenediamine
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0446554B1

  公开（公告）日：1993-10-13