triethylpropylammonium hydroxide | 115009-89-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: triethylpropylammonium hydroxide
• 英文别名: Triethyl(propyl)azanium;hydroxide
• CAS: 115009-89-7
• 化学式: C₉H₂₂N*HO
• 分子量: 161.288
• InChiKey: ZANLWQDCQMSYMT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Process for the Conversion of Oxygenates to Olefins
  申请人：BASF SE

  公开号：US20140142361A1

  公开（公告）日：2014-05-22

  The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO 2 and X 2 O 3 , wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO 2 , wherein M stands for sodium.

  本发明涉及一种将氧化物转化为烯烃的方法，包括(i)提供含有一个或多个氧化物的气流；和(ii)将气流与催化剂接触；其中催化剂包括具有MFI、MEL和/或MWW型框架结构的沸石材料，包括YO2和X2O3，其中Y是四价元素，X是三价元素，所述沸石材料可根据包括以下步骤的方法获得和/或获得：(1)准备包括一个或多个YO2来源、一个或多个X2O3来源和一个或多个溶剂的混合物；和(2)结晶步骤(1)中获得的混合物，以获得具有MFI、MEL和/或MWW型框架结构的沸石材料；其中在步骤(2)中结晶的混合物中含有基于YO2的100 wt.-%的3 wt.-%或更少的一个或多个元素M，其中M代表钠。
• Synthesis Of Chabazite Structure-Containing Molecular Sieves And Their Use In The Conversion Of Oxygenates To Olefins
  申请人：Cao Guang

  公开号：US20090018379A1

  公开（公告）日：2009-01-15

  In a method of synthesizing a silicoaluminophosphate or aluminophosphate molecular sieve comprising a CHA framework-type material, a synthesis mixture is provided comprising a source of aluminum, a source of phosphorus, optionally a source of silicon and at least one organic template of formula (I): [R 1 R 2 R 3 R 4 N] + X − (I) wherein each of R 1 , R 2 , R 3 , and R 4 is independently an acyclic alkyl group having at least one carbon atom, the total number of carbon atoms in said alkyl groups R 1 , R 2 , R 3 , and R 4 is greater than 8 but less than 16, and X − is an anion. The synthesis mixture can then be crystallized to produce the desired molecular sieve.

  在合成硅铝磷酸盐或铝磷酸盐分子筛的方法中，提供了一种包含铝源、磷源、可选的硅源和至少一种有机模板的合成混合物，该有机模板的化学式为（I）：[R1R2R3R4N]+X−（I），其中R1、R2、R3和R4分别独立地表示具有至少一个碳原子的无环烷基基团，这些烷基基团R1、R2、R3和R4中的碳原子总数大于8但小于16，X−是一种阴离子。然后可以结晶化合成混合物以产生所需的分子筛。
• Process for producing lactam
  申请人：——

  公开号：US20040215013A1

  公开（公告）日：2004-10-28

  A method for producing a lactam, which comprises subjecting an alicyclic primary amine to an oxidation reaction in the presence of a catalyst comprising a silicon oxide, to thereby obtain a lactam. A catalyst comprising a silicon oxide which is for use in the above-mentioned method.

  一种生产内酰胺的方法，包括将脂环原始胺置于存在硅氧化物催化剂的氧化反应中，从而获得内酰胺。一种包括硅氧化物的催化剂，用于上述方法。
• Lanthanum silicate materials, their production and use
  申请人：Council of Scientific and Industrial Research

  公开号：EP0225407A1

  公开（公告）日：1987-06-16

  Lanthanum silicate catalyst composites having, in terms of oxide mole ratios, the composition: 0 - 0.3 M₂O : La₂O₃ : 30-200 SiO₂ in which M is a monovalent cation. Such catalyst composites are made by reacting a lanthanum compound, an alkali metal compound and a silicon compound with a tetraalkyl ammonium salt of the formula: R¹xR²yN⁺Z in which R¹ and R² are C₂-C₄ alkyl groups, x and y are integers from 1 to 3 such that x + y is 4, and Z is a bromide or hydroxide ion, in an aqueous sulphuric acid medium to form a gel, heating the gel at a temperature of 100°C to 200°C, and filtering, drying and calcining the resulting solid material. These materials are effective catalysts for the conversion of lower alcohols to lower olefins.

  硅酸镧催化剂复合材料，其氧化物摩尔比组成如下 0 - 0.3 M₂O : La₂O₃ : 30-200 SiO₂ 其中 M 为一价阳离子。这种催化剂复合材料是通过将镧化合物、碱金属化合物和硅化合物与式中的四烷基铵盐反应制成的： R¹xR²yN⁺Z 其中 R¹ 和 R² 为 C₂-C₄烷基，x 和 y 为 1 至 3 的整数，使得 x + y 为 4，Z 为溴离子或氢氧根离子，在含水硫酸介质中形成凝胶，在 100°C 至 200°C 的温度下加热凝胶，并过滤、干燥和煅烧所得固体材料。 这些材料是低级醇转化为低级烯烃的有效催化剂。
• Process for the production of aromatic polycarbonate
  申请人：TEIJIN LIMITED

  公开号：EP0667366A2

  公开（公告）日：1995-08-16

  A process for the production of an aromatic polycarbonate, which comprises polycondensing an aromatic dihydroxy compound and a diaryl carbonate in the presence, as a polycondensation catalyst, of at least one alkali metal salt selected from the group consisting of alkali metal salts of ate-complexes of a metal element, which is silicon, germanium, stannum or plumbum, and alkali metal salts of oxoacids of said metal elements. The above aromatic polycarbonate is almost free from being colored, is also almost free from a decrease in polymerization degree when molded, and is further almost free from forming branches and insolubles.

  一种芳香族聚碳酸酯的生产工艺，包括在至少一种碱金属盐作为缩聚催化剂的存在下，将芳香族二羟基化合物和碳酸二芳基酯进行缩聚，该碱金属盐选自金属元素（硅、锗、锡或铂）的吃络合物的碱金属盐和上述金属元素的氧化物的碱金属盐组成的组。上述芳香族聚碳酸酯几乎不着色，成型时聚合度也几乎不会降低，而且几乎不会形成分支和不溶物。