bis(trimethylsilyl)silacyclopentene | 80025-05-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(trimethylsilyl)silacyclopentene
• 英文别名: Trimethyl-(1-trimethylsilyl-2,5-dihydrosilol-1-yl)silane
• CAS: 80025-05-4
• 化学式: C₁₀H₂₄Si₃
• 分子量: 228.557
• InChiKey: YKEROAASEQBVAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.84
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,3-丁二烯 在 Tris(trimethylsilyl)silyl-methylether 作用下， 生成 5-silaspiro<4.4>nona-2,7-diene 、 bis(trimethylsilyl)silacyclopentene
  参考文献：
  名称：

  1-Silacyclopent-3-en-1-ylidene，来自硅原子和硅原子合成子反应的环状亚甲硅烷基

  摘要：

  然而，现在可以直接生成 1-silacyclopent-3-en-1-ylidene (1)，它与丁二烯反应以高产率形成一种产物，我们也从硅原子的反冲和共缩合中发现了这种产物具有相同衬底的硅蒸气。本文报告了 (1) 在硅原子反应中的中介作用的新证据，这是热蒸发的硅与碳氢化合物的第一个富有成效的反应，以及硅原子合成子。

  DOI：

  10.1021/ja00414a055

文献信息

• Thermal and Photochemical [2+2] Cycloreversion of a 1,2-Disilacyclobutane and a 1,2-Digermacyclobutane
  作者：Yitzhak Apeloig、Dmitry Bravo-Zhivotovskii、Ilya Zharov、Vladislav Panov、William J. Leigh、Gregory W. Sluggett

  DOI：10.1021/ja9729600

  日期：1998.2.1

  Upon heating of the highly sterically congested 1,1,2,2-tetrakis(trimethylsilyl)dispiro[3,3',4,4'-biadamantane-1,2-disilacyclobutane] (2) in solution in the presence of trapping reagents, such as 1,3-butadienes, styrene, phenylacetylene, and methanol, the trapping products of the silene bis(trimethylsilyl)adamantylidenesilene (1) are formed with high regioselectivity and good yields. Photolysis of 2 at -196 degrees C in methylcyclohexane in the absence of trapping agents produces tetrakis(trimethylsilyl)disilene (3). Photolysis of 2 in solution in the presence of 1,3-butadiene leads to a 2:1 mixture of 1,1,2,2-tetrakis(trimethylsilyl)-1,2-disilacyclohex-4-ene (10)-the trapping product of the disilene 3-and of 1,1-bis(trimethylsilyl)-1-silocyclopent-3-ene (11)-the trapping product of bis(trimethylsilyl)silylene (4)-together with 2,2'-biadamantylidene. The results of laser flash photolysis and of additional trapping experiments suggest that the sole primary product in the photolysis of 2 is the disilene 3, which dissociates under further irradiation to produce the silylene 4. Heating of 1,1,2,2-tetrakis(trimethylsilyl)dispiro[3,3',4,4'-biadamantane-1,2-digermacyclobutane] (14) in solution results in the quantitative formation of 2,2'-biadamantylidene and of germanium-containing oligomers, while neither bis(trimethylsilyl)adamantylidenegermene (15) nor tetrakis(trimethylsilyl)digermene (16) or bis(trimethylsilyl)germylene (17) could be trapped. Upon photolysis 14 behaves similarly to 2, leading to 16 and 17, which could be trapped by 1,3-butadiene.
• GASPAR, P. P.;CHEN, YUE-CHEN;HELFER, A. P.;KONIECZNY, S.;MA, E. C. -L.;MO+, J. AMER. CHEM. SOC., 1981, 103, N 24, 7344-7345
  作者：GASPAR, P. P.、CHEN, YUE-CHEN、HELFER, A. P.、KONIECZNY, S.、MA, E. C. -L.、MO+

  DOI：——

  日期：——
• 1-Silacyclopent-3-en-1-ylidene, a cyclic silylene from the reactions of silicon atoms and a silicon atom synthon
  作者：Peter P. Gaspar、Yue Shen Chen、Adam P. Helfer、Stanislaw Konieczny、Eric C. L. Ma、Siu Hong Mo

  DOI：10.1021/ja00414a055

  日期：1981.12

  form in high yield a product which we have also found from recoiling silicon atoms and from the cocondensation of silicon vapor with the same substrate. This paper reports new evidence for the intermediacy of (1) in the reactions of silicon atoms, the first fruitful reaction of thermally evaporated silicon with a hydrocarbon, and a silicon atom synthon.

  然而，现在可以直接生成 1-silacyclopent-3-en-1-ylidene (1)，它与丁二烯反应以高产率形成一种产物，我们也从硅原子的反冲和共缩合中发现了这种产物具有相同衬底的硅蒸气。本文报告了 (1) 在硅原子反应中的中介作用的新证据，这是热蒸发的硅与碳氢化合物的第一个富有成效的反应，以及硅原子合成子。