5-(4-ethoxyphenyl)-3-(2-oxo-1,2-diphenylethylidenehydrazono)-3H-furan-2-one | 1241959-03-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 5-(4-ethoxyphenyl)-3-(2-oxo-1,2-diphenylethylidenehydrazono)-3H-furan-2-one
• CAS: 1241959-03-4
• 化学式: C₂₆H₂₀N₂O₄
• 分子量: 424.456
• InChiKey: VRMAJIGMONTEKC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (2Z)-4-(4-ethoxyphenyl)-4-oxo-2-(2-oxo-1,2-diphenylethylidenehydrazino)but-2-enoic acid 在 乙酸酐 作用下， 以93%的产率得到5-(4-ethoxyphenyl)-3-(2-oxo-1,2-diphenylethylidenehydrazono)-3H-furan-2-one
  参考文献：
  名称：

  Chemistry of iminofurans: V. Synthesis, structure, and cyclization of 4-R-4-oxo-2-[2-(2-oxo-1,2-diphenylethylidene)hydrazino]but-2-enoic acids

  摘要：

  Reactions of 1,2-diphenylethane-1,2-dione hydrazone with 4-aryl-2-hydroxy-4-oxobut-2-enoic and 2-hydroxy-5,5-dimethyl-4-oxohex-2-enoic acids provided 4-aryl-4-oxo-2-[2-(2-oxo-1,2-diphenylethylidene) hydrazino]but-2-enoic and 5,5-dimethyl-4-oxo-2-[2-(2-oxo-1,2-diphenylethylidene)hydrazino]hex-2-enoic acids. The acids derivatives can exist in solutions as Z- and beta-enehydrazino-or beta-ketohydrazone forms, and under the treatment with acetic anhydride they undergo cyclization into 5-aryl- and 5-tert-butyl-3-[2-(2-oxo-1,2-diphenylethylidene)hydrazono]-2,3-furandiones.

  DOI：

  10.1134/s1070428010020156