[Nd2(glutarate)3(1,10-phenanthroline)2](n) | 528840-52-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Nd2(glutarate)3(1,10-phenanthroline)2](n)
• 英文别名: [Nd2(glu)3(phen)2](n)
• CAS: 528840-52-0
• 化学式: C₃₉H₃₄N₄Nd₂O₁₂
• 分子量: 1039.2
• InChiKey: RWFIEIKCNRQNEA-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  戊二酸 、 1,10-菲罗啉 、 neodymium(III) chloride hexahydrate 在 NaOH 作用下， 以 水 为溶剂， 以47%的产率得到[Nd2(glutarate)3(1,10-phenanthroline)2](n)
  参考文献：
  名称：

  Hydrothermal synthesis and crystal structures of three novel lanthanide coordination polymers with glutarate and 1,10-phenanthroline

  摘要：

  The first series of lanthanide coordination polymers with glutarate (glu) and 1, 10-phenanthroline (phen), [Nd-2(glu)(3)(phen)(2)](n) 1, [Tb(glu)(phen)Cl](n) 2 and [Ho(glu)(phen)Cl](n) 3, have been prepared by hydrothermal reaction and characterised by IR spectra and X-ray crystallography. In complex 1, there are two different conformations for glutarate ligands, the gauche- and anti-forms. Nd(III) ions are bridged by glutarate ligands in three modes to form 2D layer structure. Phen ligands coordinate to Nd(III) ions in chelating mode and protrude from the polymeric layer in two different directions. Two types of pi-pi interactions exist between two adjacent layers. In complex 2, Tb(III) ions are connected by glutarate ligands into 1D chain structure. Phen ligands coordinate to Tb(III) ions in chelating mode and locate at both sides of the chain. The C-(HO)-O-..., C-(HCl)-Cl-... weak hydrogen bonds and pi-pi stacking interactions between chains result in 3D supramolecular structure. Single-crystal X-ray diffraction analysis shows that complex 3 is isostructural with complex 2. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00614-2