nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-diol | 120742-39-4

分子结构分类

有机化合物 - 苯类化合物 - 并四苯

中文名称

——

中文别名

——

英文名称

nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-diol

英文别名

——

nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-diol化学式

CAS

120742-39-4

化学式

C₇₀H₄₆O₂

mdl

——

分子量

919.134

InChiKey

DYRYSFSTPYCLEB-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

13.5
重原子数：

72
可旋转键数：

0
环数：

23.0
sp3杂化的碳原子比例：

0.17
拓扑面积：

40.5
氢给体数：

2
氢受体数：

2

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-dione	120742-38-3	C₇₀H₄₂O₂	915.102

反应信息

作为反应物：

描述：

nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-diol 在吡啶、三氯氧磷作用下，以二氯甲烷为溶剂，反应 17.0h，生成 noniptycene

参考文献：

名称：

Iptycene synthesis. A new method for attaching a 2,3-anthracene moiety to the 9,10-positions of another anthracene moiety. Exceptional conditions for a Lewis acid-catalyzed Diels-Alder reaction

摘要：

DOI：

10.1021/jo00272a030
作为产物：

描述：

nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-dione 在 lithium aluminium tetrahydride 作用下，以四氢呋喃为溶剂，反应 17.0h，生成 nonadecacyclo[22.14.14.65,20.628,35.642,49.02,23.04,21.06,19.08,17.010,15.025,38.027,36.029,34.039,52.041,50.043,48.053,58.059,64.065,70]heptaconta-2(23),3,8,10,12,14,16,21,25(38),26,29,31,33,36,39(52),40,43,45,47,50,53,55,57,59,61,63,65,67,69-nonacosaene-7,18-diol

参考文献：

名称：

Iptycene synthesis. A new method for attaching a 2,3-anthracene moiety to the 9,10-positions of another anthracene moiety. Exceptional conditions for a Lewis acid-catalyzed Diels-Alder reaction

摘要：

DOI：

10.1021/jo00272a030

点击查看最新优质反应信息

文献信息

CHEN, YONG-SHING;HART, HAROLD, J. ORG. CHEM., 54,(1989) N1, C. 2612-2615

作者：CHEN, YONG-SHING、HART, HAROLD

DOI：——

日期：——

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