(S)-2,2'-dimethoxy-1,1'-binaphthyl-3,3'-bis(4-vinylpyridine) | 615536-35-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (S)-2,2'-dimethoxy-1,1'-binaphthyl-3,3'-bis(4-vinylpyridine)
• CAS: 615536-35-1
• 化学式: C₃₆H₂₈N₂O₂
• 分子量: 520.631
• InChiKey: KWPBFQMBVQVLQU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.81
• 重原子数：
  40.0
• 可旋转键数：
  7.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  44.24
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (S)-2,2'-dimethoxy-1,1'-binaphthyl-3,3'-bis(4-vinylpyridine) 、 silver nitrate 以 乙醇 、 二甲基亚砜 为溶剂， 以83.4%的产率得到Ag((S)-2,2'-dimethoxy-1,1'-binaphthyl-3,3-bis(4-vinylpyridine))2(NO3)
  参考文献：
  名称：

  Luminescent homochiral silver(i) lamellar coordination networks built from helical chains

  摘要：

  2,2'-二甲氧基-1,1'-联萘-3,3'-双(4-乙烯基吡啶)的反应 (L) 与 AgNO3 或 AgClO4 在 70 °C 下生成两种新型发光纯手性层状配位聚合物 AgL2X（X = NO3− 为 1 或 ClO4− 为 2），它们是由 Ag(I) 原子连接螺旋链构建而成作为铰链。

  DOI：

  10.1039/b403609c

文献信息

• A homochiral triple helix constructed from an axially chiral bipyridineElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b212781d/
  作者：Yong Cui、Helen L. Ngo、Wenbin Lin

  DOI：10.1039/b212781d

  日期：——

  A homochiral triple helix was self-assembled from an axially chiral bipyridine and a linear metal-connecting point, which further assembles into a 2D network via infinite π⋯π stacking interactions and acts as a host for the inclusion of guest molecules.

  一个均齿三重螺旋由轴向手性二吡啶和线性金属连接点自组装而成，随后通过无限的π⋯π堆积相互作用组装成一个二维网络，并作为包容 guest 分子的宿主。
• Self-Assembly of Homochiral Porous Solids Based on 1D Cadmium(II) Coordination Polymers
  作者：Chuan-De Wu、Wenbin Lin

  DOI：10.1021/ic048671b

  日期：2005.3.1

  A family of homochiral 1D cadmium(II) coordination polymers based on the (S)-2,2'-dimethoxy-1,1'-binaphthyl-3,3'-bis(4-vinylpyridine) (L) bridging ligand were synthesized from the same building blocks under slightly different conditions, and characterized by single-crystal X-ray crystallography. While [CdL(DMF)(4)](ClO4)(2).EtOH.0.5H(2)O (1) adopts a 1D zigzag chain structure, [CdL2(ClO4)(2)].3EtOH.H2O (2) and [CdL2(ClO4)(H2O)] (ClO4).1.5(o-C6H4Cl2).3EtOH.6H(2)O (3) both exhibit 1D polymeric structures that are built from 38-membered macrocycles. These 1D coordination polymers further pack into chiral porous frameworks via pi..pi interactions with a large percentage of void spaces that are occupied by solvent molecules and counterions.