| 1354559-86-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1354559-86-6
• 化学式: C₂₈H₅₆N₆NiO₄
• 分子量: 599.48
• InChiKey: DYYIKJJSVJJBSF-OBRUGXQASA-L

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 在 KOH 作用下， 以 乙醇 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Alkyl-substituted oxamide oximes and their metal complexes

  摘要：

  Nickel(11) and palladium(II) complexes of oxamide oximes substituted with alkyl chains of different length (CnH2n+1, n = 4, 6, 8, 10, 12 and 16) have been synthesized from the reaction of (E,E)-monochloroglyoxime with the corresponding amine derivatives. The Ni(II) and Pd(11) complexes have been prepared by reacting the ligand with either NiCl2 center dot 6H(2)O or Na2PdCl4 in ethanol. All the compounds were characterized by elemental analyses, H-1 NMR, IR and mass spectra. The molecular structure of bis[(N-hexylaminoglyoxime)]palladium(II) (2b) was obtained by single crystal X-ray diffraction and it was found to be centrosymmetric at the metal center, which is bound by the four oximic nitrogen atoms of two ligands in a square planar environment. The role of the H-bonding in the structures of these complexes was investigated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.019