bis[1,1-di(2-pyridyl)ethyl]amine | 302541-88-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis[1,1-di(2-pyridyl)ethyl]amine
• 英文别名: N-(1,1-dipyridin-2-ylethyl)-1,1-dipyridin-2-ylethanamine
• CAS: 302541-88-4
• 化学式: C₂₄H₂₃N₅
• 分子量: 381.48
• InChiKey: XEAXOSLCDVWHGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  bis[1,1-di(2-pyridyl)ethyl]amine 、 cobalt(II) diacetate tetrahydrate 以 甲醇 、 乙腈 为溶剂， 以86%的产率得到triacetato-bis[1,1-di(2-pyridyl)ethyl]amido(μ-hydroxo)dicobalt dihydrate
  参考文献：
  名称：

  空前的酰胺桥双核混合价钴配合物：双核μ-OMeCo（II）/ Co（III）配合物的第一结构

  摘要：

  五齿配体双[1,1-二（2-吡啶基）乙基]胺（BDPEA）与钴（II）盐的络合生成新型Co（II）/ Co（III）混合价络合物：仲起始BDPEA的胺被去质子化，导致成核的桥联酰胺配体。

  DOI：

  10.1039/b007907n

文献信息

• Enzymatic detergent compositions
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20030050211A1

  公开（公告）日：2003-03-13

  There is provided an enzymatic detergent composition which comprises: (a) surfactant; (b) 10-20,000 LU per gram of the detergent composition of a lipolytic enzyme obtainable from Humicola lanuginosa, Pseudomonas pseudoalcaligenes, Rhizomucor miehei and (c) a non-cross-bridged polydentate N-donor ligand capable of forming a complex with a transition metal, wherein said complex is capable of catalysing the bleaching of stains on fabrics by means of atmospheric oxygen.

  提供了一种酶性洗涤剂组合物，其包括：（a）表面活性剂；（b）每克洗涤剂组合物10-20,000 LU的脂肪水解酶，可从Humicola lanuginosa，Pseudomonas pseudoalcaligenes，Rhizomucor miehei中获得；以及（c）一种非交联多齿N-给体配体，能够与过渡金属形成配合物，该配合物能够通过大气氧气催化漂白织物上的污渍。
• COMPOSITION AND METHOD FOR BLEACHING A SUBSTRATE
  申请人：UNILEVER PLC

  公开号：EP1165738B1

  公开（公告）日：2005-07-27
• ENZYMATIC DETERGENT COMPOSITIONS
  申请人：UNILEVER N.V.

  公开号：EP1341893B1

  公开（公告）日：2007-05-02
• US6617299B1
  申请人：——

  公开号：US6617299B1

  公开（公告）日：2003-09-09
• [EN] COMPOSITION AND METHOD FOR BLEACHING A SUBSTRATE<br/>[FR] COMPOSITION ET PROCEDE POUR BLANCHIR UN SUBSTRAT
  申请人：UNILEVER PLC

  公开号：WO2000060044A1

  公开（公告）日：2000-10-12

  The invention relates to catalytically bleaching substrates, especially laundry fabrics, with atmospheric oxygen or air. A method of bleaching a substrate is provided that comprises applying to the substrate, in an aqueous medium, a specified ligand from a selected class which forms a complex with a transition metal, the complex catalysing bleaching of the substrate by atmospheric oxygen. Also provided is an aqueous bleaching composition substantially devoid of peroxygen bleach or a peroxy-based or generating bleach system. Also provided is a method of treating a textile such as a laundry fabric whereby a complex catalyses bleaching of the textile by atmospheric oxygen after the treatment. The catalyst may be used in dry form, or in a liquor that is then dried, such as an aqueous spray-on fabric treatment fluid or a wash liquor for laundry cleaning, or a non-aqueous dry cleaning fluid or spray-on aerosol fluid. The method can confer cleaning benefits to the textile after the treatment. Also provided is a dry textile having a catalyst applied or deposited thereon, whereby bleaching by atmospheric oxygen is catalysed on the textile.