1,5-naphthalenedisulfonate anion | 22713-47-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,5-naphthalenedisulfonate anion
• 英文别名: 1,5-naphthalene disulfonate；naphthalene-1,5-disulfonate；1,5-naphthalenedisulfonate；1,5-NDS；naphthalene-1,5-disulfonic acid dianion；Naphthalin-1.5-disulfonat
• CAS: 22713-47-9
• 化学式: C₁₀H₆O₆S₂
• 分子量: 286.286
• InChiKey: XTEGVFVZDVNBPF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  131
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1.6.20.25-四偶氮[6.1.6.1]环苯 、 1,5-naphthalenedisulfonate anion 生成 naphthalene-1,5-disulfonate;7,12,22,27-tetrazapentacyclo[26.2.2.23,6.213,16.218,21]octatriaconta-1(30),3(38),4,6(37),13(36),14,16(35),18,20,28,31,33-dodecaene
  参考文献：
  名称：

  KOGA, KENJI;ODASHIMA, KAZUNORI, J. INCL. PHENOM., 7,(1989) N, C. 53-60

  摘要：

  DOI：
• 作为试剂：
  描述：

  3,3-bis-fluoromethyl-1-bromo-1-(4-chlorophenoxy)-butan-2-one 、 咪唑 、 1,5-萘二磺酸(四水合物) 在 水 、 Sodium sulfate-III 、 1,5-naphthalenedisulfonate anion 、 compound 、 碳酸氢钠 作用下， 以 乙腈 为溶剂， 反应 4.0h， 以14 g (24% of theory) of 3,3-bis-fluoromethyl-1-(4-chlorophenoxy)-1-(imidazol-1-yl)-butan-2-one were obtained as a viscous oil的产率得到3,3-bis-fluoromethyl-1-(4-chlorophenoxy)-1-(imidazol-1-yl)-butan-2-one
  参考文献：
  名称：

  Combating fungi with 1-phenoxy -1-imidazol-1-yl-4-fluoro-butane

  摘要：

  具有杀菌性能的公式为##STR1##的1-Phenoxy-1-imidazol-1-yl-4-fluoro-butane衍生物，其中B为--CO-或--CH(OH)--，X为氢或氟，Z各自独立为卤素，烷基，硝基，氰基，烷氧基-羰基或可选取代的苯基，n为0，1，2或3，或其酸或金属盐加合物。

  公开号：

  US04419361A1

文献信息

• Fluorescent ligand design for mononuclear copper(I) complex fluorescence in aqueous solution
  作者：Makoto Saga、Genta Sakane、Shigeo Yamazaki、Keiitsu Saito

  DOI：10.1016/j.ica.2019.119368

  日期：2020.3

  these Cu(II) complexes were synthesized. The fluorescence of [Cu(I/II)(qdeta)]+/2+ and [Cu(I/II)(bpqa)]+/2+ in aqueous solution was characterized; [Cu(I)(qdeta)]+ and [Cu(I)(bpqa)]+ were found to fluoresce in aqueous solution, whereas the fluorescence of [Cu(II)(qdeta)]2+ and [Cu(II)(bpqa)]2+ was almost completely quenched. The chelation enhanced fluorescence effect was observed for both [Cu(I)(qdeta)]+

  摘要合成了荧光配体3-（2-甲基喹啉基）二亚乙基三胺（QDETA）和双（2-吡啶基甲基）（2-喹啉基甲基）胺（BPQA），并合成了这些Cu（II）配合物。表征了水溶液中[Cu（I / II）（qDETA）] + / 2+和[Cu（I / II）（bpqa）] + / 2+的荧光。发现[Cu（I）（qDETA）] +和[Cu（I）（bpqa）] +在水溶液中发荧光，而[Cu（II）（qDETA）] 2+和[Cu（II） （bpqa）] 2+几乎被完全淬灭。对于[Cu（I）（qDETA）] +和[Cu（I）（bpqa）] +均观察到螯合增强了荧光作用。通过单晶X射线晶体学表征五配位的Cu（II）络合物[Cu（II）（qDETA）（H 2 O）] NDSA·2H 2 O（NDSA ＝ 1，5-萘二磺酸根阴离子）。
• Synthesis, structure, characterization, and multifunctional properties of a family of rare earth organic frameworks
  作者：Haoran Li、Tianlu Sheng、Zhenzhen Xue、Xiaoquan Zhu、Shengmin Hu、Yuehong Wen、Ruibiao Fu、Chao Zhuo、Xintao Wu

  DOI：10.1039/c7ce00202e

  日期：——

  A series of isomorphic 3D layered rare earth hydroxide (LREH) frameworks RE3(OH)7(1,5-NDS) (RE = Y (1), Gd (2), Er (3), Yb (4); 1,5-NDS = 1,5-naphthalenedisulfonate) has been synthesized under hydrothermal conditions. The crystal structures, thermal stabilities, photoluminescence, and magnetic properties of these compounds have been investigated. The results demonstrate that the compounds are highly

  一系列同构3D层状稀土氢氧化物（LREH）骨架RE 3（OH）7（1,5-NDS）（RE = Y（1），Gd（2），Er（3），Yb（4）; 1 （5-NDS ＝ 1，5-萘二磺酸盐）已在水热条件下合成。已经研究了这些化合物的晶体结构，热稳定性，光致发光和磁性。结果表明，该化合物即使在351°C时也非常稳定，并发出强烈的紫色荧光，其颜色可通过配位的稀土离子进行调节。还测量了它们的磁化率，使该化合物成为有前途的多功能材料。
• Two M(II)-1,5-NDS-dafo supramolecular architectures (M = Cu, Cd): syntheses, structures, and photoluminescence properties
  作者：Shuai Shao、Yu-Lan Zhu、Kui-Rong Ma、Hui-Chao Zhao、Yong-Qing Qiu

  DOI：10.1080/00958972.2013.813938

  日期：2013.8.1

  Under hydrothermal conditions, reaction of Cu(II)/Cd(II) salts with 1,5-naphthalenedisulfonate (1,5-NDS) and 4,5-diazafluoren-9-one (dafo) afforded [Cu(dafo)(2)(1,5-NDS)](n) (1) and [Cd(dafo)(2)(1,5-NDS)](n) (2), respectively. The compounds were characterized by elemental analysis, IR, PXRD, TG-DSC, and single-crystal X-ray diffraction. Both 1 and 2, which are the first M(II)-1,5-NDS-dafo systems, exhibit 3-D supramolecular structures generated by 1-D chains via C-HO hydrogen bonds and - interactions. Solid-state photoluminescence properties of both 1 and 2 were investigated with emission bands at 426-496nm ((ex)=280, 270nm for 1 and 2, respectively).
• Syntheses, structures, and photoluminescence properties of Zn(II)/Cd(II) supramolecular architectures based on 1,5-naphthalenedisulfonate and 1,10-phenanthroline ligands
  作者：Yulan Zhu、Shuai Shao、Kuirong Ma、Huichao Zhao、Yongqing Qiu

  DOI：10.1007/s00706-013-1037-0

  日期：2013.10

  Two new supramolecular transition metal compounds, [Zn(phen)(2)(1,5-NDS)(H2O)] and [Cd(phen)(2)(1,5-NDS)](n) (1,5-NDS = 1,5-naphthalenedisulfonate, phen = 1,10-phenanthroline), were obtained under hydrothermal/solvothermal conditions and structurally characterized by elemental analysis, IR, PXRD, TG-DSC, and single-crystal X-ray determination. They represent the first examples of Zn(II)/Cd(II) supramolecular compounds based on the 1,5-NDS/phen system. The Zn compound exhibits a 3D supramolecular structure via hydrogen bond (O-Ha <-O and C-Ha <-O) and pi-pi interactions. The Cd compound is a 3D supramolecular framework generated by 1D coordinated chains through a hydrogen bond (C-Ha <-O) and pi-pi interactions. In addition, photoluminescence properties for both have been discussed. [Zn(phen)(2)(1,5-NDS)(H2O)] shows an emission peak at 420 nm (lambda (ex) = 342 nm), and [Cd(phen)(2)(1,5-NDS)] (n) displays a strong emission peak at 388 nm with a shoulder peak at 369 nm (lambda (ex) = 332 nm)..
• Cage‐To‐Cage Transformations in Self‐Assembled Coordination Cages Using “Acid/Base” or “Guest Binding‐Induced Strain” as Stimuli
  作者：Vellaiyadevan Sivalingam、Minaz Parbin、Shobhana Krishnaswamy、Dillip Kumar Chand

  DOI：10.1002/anie.202403711

  日期：2024.6.3

  Controlling supramolecular systems between different functional forms by utilizing acids/bases as stimuli is a formidable challenge, especially where labile coordination bonds are involved. A pair of acid/base responsive, interconvertible 1,5‐enedione/pyrylium based Pd2L4‐type cages are prepared that exhibit differential guest binding abilities towards disulfonates of varied sizes. A three‐state switch has been achieved, where (i) a weakly coordinating base induced cage‐to‐cage transformation in the first step, (ii) a strongly coordinating base triggered cage disassembly as the second step, and (iii) the third step shows acid(strong) promoted generation of initial cage, thereby completing the cycle. To our surprise, binding of a specific disulfonate guest facilitated cage‐to‐cage transformations by inducing strain on the cage assembly thereby opening the labile pyrylium rings of the cage. Through competitive guest binding study, we demonstrated superior guest binding capability of octa‐cationic pyrylium‐based cage over a similar‐sized tetra‐cationic cage. These results provide a reliable approach to reversibly modulate the guest binding properties of acid/base‐responsive self‐assembled coordination cages.

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