(2S,3R,4S,5S,6R)-2-azido-2-benzyl-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran | 1259515-57-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3R,4S,5S,6R)-2-azido-2-benzyl-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran
• CAS: 1259515-57-5
• 化学式: C₄₁H₄₁N₃O₅
• 分子量: 655.794
• InChiKey: YFKMHPSHWBJZMQ-RSGFCBGISA-N

反应信息

• 作为产物：
  描述：

  (3R,4S,5S)-2-benzyl-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-ol 在 叠氮基三甲基硅烷 、 碘 作用下， 以 二氯甲烷 为溶剂， 以76%的产率得到(2S,3R,4S,5S,6R)-2-azido-2-benzyl-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran
  参考文献：
  名称：

  Molecular iodine-promoted N- and C-glycosylation of 1-C-alkyl (or phenyl)-glycopyranoses

  摘要：

  Molecular iodine efficiently promoted the N- and C-glycosylation of hemiketals with Me3SiN3 and Me3SiCN, respectively. Using this method we have prepared diverse functional N- and C-ketosides, which could serve as useful synthons for the preparation of unnatural glycosyl amino acids or glycopeptides. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.124