Cd(glutarate)(1,10-phenanthroline)H2O | 928622-66-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: Cd(glutarate)(1,10-phenanthroline)H2O
• CAS: 928622-66-6
• 化学式: C₅H₆O₄*C₁₂H₈N₂*Cd*H₂O
• 分子量: 440.734
• InChiKey: INNAAXAFHYTHAH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.39
• 重原子数：
  25.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  137.54
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  戊二酸 、 1,10-菲罗啉 、 aqueous cadmium chloride 在 NaOH 作用下， 以 水 为溶剂， 以71%的产率得到Cd(glutarate)(1,10-phenanthroline)H2O
  参考文献：
  名称：

  New photoluminescence coordination polymers constructed from different ligands, which are generated from maleic acid at hydrothermal conditions

  摘要：

  A new coordination polymer, [Zn-2(mal)(1,10-phen)Cl](n) (1), (mal = malate, 1,10-phenanthroline), has been synthesized with malic acid and fumaric acid which are generated from maleic acid under hydrothermal reactions. At about the same condition, we get [Cd(fma)(2,2'-bpy)(H2O)] (2) (fma = fumarate, 2,2'-bpy=2, 2'-bipyridine). The diverse products illustrate that the carbon-carbon doublebond of the maleic acid has two kinds of reaction trends under different conditions. Complex 1, which displays a two-dimensional (4, 8) lattice-type network, is formed from Zn and maleic through the addition reaction with water molecule. If the Zn is changed by Cd, at the same reaction condition with 1, a two-dimensional supramolecular network complex 2 is formed through the conformation transform reaction. To our knowledge, a lot of coordination polymers have been constructed from malic acid and fumaric acid directly; however, these kinds of complexes have seldom been synthesized from maleic acid under hydrothermal reaction. As is known, the rigid carbon-carbon double bond makes maleic acid lead to some unique structural features which the saturated aliphatic acid does not possess. To illustrate this clearly, a simple one dimensional complex 3, [Cd(glut)(1,10-phen)(H2O)] (glut =glutarate), is synthesized. Furthermore, complex 1 and complex 3 exhibit intense photoluminescent property at room temperature. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.07.111