[Cu(bis(3-tert-butyl-5-isopropyl-1-pyrazolyl)methane)(NO3)2] | 1023596-22-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(bis(3-tert-butyl-5-isopropyl-1-pyrazolyl)methane)(NO3)2]
• CAS: 1023596-22-6
• 化学式: C₂₁H₃₆CuN₆O₆
• 分子量: 532.099
• InChiKey: QXCHLWGGSKYIKJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 bis(3-tert-butyl-5-isopropyl-1-pyrazolyl)methane 以 二氯甲烷 、 丙酮 为溶剂， 以63%的产率得到[Cu(bis(3-tert-butyl-5-isopropyl-1-pyrazolyl)methane)(NO3)2]
  参考文献：
  名称：

  Copper(II) complexes with neutral bis(pyrazolyl)methane ligands: The influence of steric hindrance on their structures and properties

  摘要：

  By using the neutral bidentate nitrogen-containing ligands; bis(3,5-dimethyl-1-pyrazolyl)methane (L0"), bis(3,5-diisopropyl-1-pyrazolyl)methane (L1"), bis(3-tertiary-butyl-5-isopropyl-1-pyrazolyl)methane (L3"), and bis(3,5-ditertiary-butyl-1-pyrazolyl)methane (L4"), the copper(II) nitrato complexes [Cu(L0")(2)(NO3)]NO3 (1NO(3)), [Cu(L0")(NO3)(2)] (2), [Cu(L1")(NO3)(2)] (3), [Cu(L3")(NO3)(2)] (4), and [Cu(L4")(NO3)(2)] (5), chloro complexes [Cu(L0")(2)Cl](2)(CuCl4) (6CuCl(4)), [Cu(L0")(2)Cl](2)(Cu2Cl6) (6Cu(2)Cl(6)), [Cu(L1")Cl-2] (7), and [Cu(L3")Cl-2] (8), nitrito complexes [Cu(L0")(ONO)(2)] (9) and [Cu(L1")(ONO)(2)] (10), and the complexes with perchlorate ions [Cu(L0")(2)(CH3OH)](ClO4)(2) (11ClO(4)) and [Cu(L1")(2)(H2O)](ClO4)(2) (12ClO(4)) were systematically synthesized and fully characterized by X-ray crystallography and by IR, far-IR, UV-Vis absorption, and ESR spectroscopy. In comparison with the obtained complexes with four bis(pyrazolyl)methanes having different bulkiness at pyrazolyl rings, the second coordination sphere effects on the ligands are discussed in detail. Moreover, the structures and physicochemical properties of these obtained complexes are compared with those of the related complexes with the neutral tridentate tris(pyrazolyl)methane ligand. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.01.019