[RhCl(pyz)2(Me3[9]aneN3)] | 278608-82-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [RhCl(pyz)2(Me3[9]aneN3)]
• 英文别名: chlororhodium(2+);pyrazol-2-ide;1,4,7-trimethyl-1,4,7-triazonane
• CAS: 278608-82-5
• 化学式: C₁₅H₂₇ClN₇Rh
• 分子量: 443.785
• InChiKey: MNSCNQREVZSUOG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris(acetone){η5-(pentamethylcyclopentadienyl)}rhodium trifluoromethanesulfonate 、 [RhCl(pyz)2(Me3[9]aneN3)] 以 甲醇 、 丙酮 为溶剂， 以41%的产率得到[[Rh(Me3[9]aneN3)](μ-Cl)(μ-pyz)2[Rh(η5-C5Me5)]](CF3SO3)2
  参考文献：
  名称：

  Solvolysis, structure and reactivity of (1,4,7-trimethyl-1,4,7-triazacyclononane)rhodium(III) complexes [RhCl3−xLx(Me3[9]aneN3)](x)+ (L=CH3CN, DMSO, DMF) and [RhCl(pyz)2(Me3[9]aneN3)] (Hpyz=pyrazole)

  摘要：

  Treatment of [RhCl3(Me-3[9]aneN(3))] (1) (Me[9]aneN(3) = 1,4,7-trimethyl-1,4,7-triazacyclononane) with Ag(CF3SO3) in a 1:3 ratio at 60 degrees C for 30 min in CH3CN leads to formation of the tetranuclear complex [{RhCl3(Me-3[9]aneN(3))}(2)Ag-2(CF3 SO3)(CH3CN)](CF3SO3). CH3CN (2) with a novel Rh2Ag2Cl6 core. More forcing conditions (reflux, 18 h) afford the likewise tetranuclear complex [{RhCl2(CH3CN)(Me-3[9]aneN(3))}(3)Ag](CF3 SO3)(4) (3) with an alternative Rh3AgCl6 central unit. Whereas only one Cl- ligand can also be substituted under similar conditions in DMSO to provide trinuclear [{RhCl2(DMSO-kappa O)(Me-3[9]aneN(3))} Ag-2(CH3OH)](CF3SO3)(3) (4), performing the reaction in the more polar solvent DMF allows two chlorides to be removed thereby yielding mononuclear [RhCl(DMF)(2)(Me-3[9]aneN(3))](CF3SO3)(2) (5). The coordinated DMF ligands are transformed to CH3NHCHO in [RhCl(CH3NHCHO)(2)(Me-3[9]aneN(3))](CF3SO3)(2) (6) on treating 5 with methylamine. [RhCl(mu-pyz)(2)(Me-3[9]aneN(3))] (7) (pyz=pyrazolate) reacts with (eta(5)-C5Me5)M(III) fragments to generate the dinuclear complexes [{Rh(Me-3[9]aneN(3))} (mu-Cl)(mu-pyz)(2){M(eta(5)-C5Me5)}](CF3SO3)(2) 8 and 9 (M = Rh, Ir). X-ray structures have been determined for 2-8. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00075-x
• 作为产物：
  描述：

  吡唑 、 trichloro(N,N',N''-trimethyl-1,4,7-trazacyclononane)rhodium(III) 在 KOH 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以55%的产率得到[RhCl(pyz)2(Me3[9]aneN3)]
  参考文献：
  名称：

  Solvolysis, structure and reactivity of (1,4,7-trimethyl-1,4,7-triazacyclononane)rhodium(III) complexes [RhCl3−xLx(Me3[9]aneN3)](x)+ (L=CH3CN, DMSO, DMF) and [RhCl(pyz)2(Me3[9]aneN3)] (Hpyz=pyrazole)

  摘要：

  Treatment of [RhCl3(Me-3[9]aneN(3))] (1) (Me[9]aneN(3) = 1,4,7-trimethyl-1,4,7-triazacyclononane) with Ag(CF3SO3) in a 1:3 ratio at 60 degrees C for 30 min in CH3CN leads to formation of the tetranuclear complex [{RhCl3(Me-3[9]aneN(3))}(2)Ag-2(CF3 SO3)(CH3CN)](CF3SO3). CH3CN (2) with a novel Rh2Ag2Cl6 core. More forcing conditions (reflux, 18 h) afford the likewise tetranuclear complex [{RhCl2(CH3CN)(Me-3[9]aneN(3))}(3)Ag](CF3 SO3)(4) (3) with an alternative Rh3AgCl6 central unit. Whereas only one Cl- ligand can also be substituted under similar conditions in DMSO to provide trinuclear [{RhCl2(DMSO-kappa O)(Me-3[9]aneN(3))} Ag-2(CH3OH)](CF3SO3)(3) (4), performing the reaction in the more polar solvent DMF allows two chlorides to be removed thereby yielding mononuclear [RhCl(DMF)(2)(Me-3[9]aneN(3))](CF3SO3)(2) (5). The coordinated DMF ligands are transformed to CH3NHCHO in [RhCl(CH3NHCHO)(2)(Me-3[9]aneN(3))](CF3SO3)(2) (6) on treating 5 with methylamine. [RhCl(mu-pyz)(2)(Me-3[9]aneN(3))] (7) (pyz=pyrazolate) reacts with (eta(5)-C5Me5)M(III) fragments to generate the dinuclear complexes [{Rh(Me-3[9]aneN(3))} (mu-Cl)(mu-pyz)(2){M(eta(5)-C5Me5)}](CF3SO3)(2) 8 and 9 (M = Rh, Ir). X-ray structures have been determined for 2-8. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00075-x