methyl 1,4-dihydro-1,2,3,4-tetrafluoro-1,4-ethanophenazine-11-carboxylate | 1015789-75-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: methyl 1,4-dihydro-1,2,3,4-tetrafluoro-1,4-ethanophenazine-11-carboxylate
• CAS: 1015789-75-9
• 化学式: C₁₆H₁₀F₄N₂O₂
• 分子量: 338.261
• InChiKey: XPWMQXGOCMJAJY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 邻苯二胺 以 苯 为溶剂， 反应 0.08h， 生成 methyl 1,4-dihydro-1,2,3,4-tetrafluoro-1,4-ethanophenazine-11-carboxylate
  参考文献：
  名称：

  o-Fluoranil Chemistry: Diels–Alder versus Hetero-Diels–Alder Cycloaddition

  摘要：

  The title quinone undergoes [4 + 2] cycloadditions in two ways, Diels-Alder on the ring and hetero-Diels-Alder by attack at the oxygens. The latter mode of reaction is strongly favored thermodynamically, but there is a kinetic bias favoring the normal Diels-Alder addition that often prevails, especially with cycloaddends that are not electron-rich.

  DOI：

  10.1021/jo7026678