(3S,6S)-2,5-diethoxy-3,6-dihydro-3,6-diisopropyl-6-methylsulfanylpyrazine | 1233192-54-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 甲亚胺酸及其衍生物
• 英文名称: (3S,6S)-2,5-diethoxy-3,6-dihydro-3,6-diisopropyl-6-methylsulfanylpyrazine
• CAS: 1233192-54-5
• 化学式: C₁₅H₂₈N₂O₂S
• 分子量: 300.466
• InChiKey: HUMZLCOPPRWRRO-WFASDCNBSA-N

反应信息

• 作为反应物：
  描述：

  (3S,6S)-2,5-diethoxy-3,6-dihydro-3,6-diisopropyl-6-methylsulfanylpyrazine 在 三氟乙酸 作用下， 以 乙醇 为溶剂， 以31%的产率得到2,5-diethoxy-3,6-diisopropylpyrazine
  参考文献：
  名称：

  Synthesis of (3S)-2,5-Diethoxy-3,6-dihydro-3-isopropyl-6-methylsulfanylpyrazines and Stereoselectivity in Alkylation of the Anions

  摘要：

  The introduction of a sulfur function into Schollkopf's bislactim ether was carried out to synthesize the diastereomers of (3S)-2,5-diethoxy-3,6-dihydro-3-isopropyl-6-methylsulfanylpyrazine. Stereoselectivity in the alkylation of the anions derived from those compounds was examined as a basic study of the synthesis of chiral alpha-sulfanylamino acids.

  DOI：

  10.3987/com-10-11922
• 作为产物：
  描述：

  2-碘代丙烷 、 (3S)-2,5-diethoxy-3,6-dihydro-3-isopropyl-6-methylsulfanylpyrazine 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以65%的产率得到(3S,6S)-2,5-diethoxy-3,6-dihydro-3,6-diisopropyl-6-methylsulfanylpyrazine
  参考文献：
  名称：

  Synthesis of (3S)-2,5-Diethoxy-3,6-dihydro-3-isopropyl-6-methylsulfanylpyrazines and Stereoselectivity in Alkylation of the Anions

  摘要：

  The introduction of a sulfur function into Schollkopf's bislactim ether was carried out to synthesize the diastereomers of (3S)-2,5-diethoxy-3,6-dihydro-3-isopropyl-6-methylsulfanylpyrazine. Stereoselectivity in the alkylation of the anions derived from those compounds was examined as a basic study of the synthesis of chiral alpha-sulfanylamino acids.

  DOI：

  10.3987/com-10-11922