[Cd(dipyrido[3,2-a2',3'-c]phenazine)(benzene-1,2-dioxyacetate)] | 1228341-14-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [Cd(dipyrido[3,2-a2',3'-c]phenazine)(benzene-1,2-dioxyacetate)]
• 英文别名: [Cd(dppz)(bdoa)]
• CAS: 1228341-14-7
• 化学式: C₁₀H₈O₆*C₁₈H₁₀N₄*Cd
• 分子量: 618.884
• InChiKey: DIANSBIGGVMMED-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.82
• 重原子数：
  39.0
• 可旋转键数：
  6.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  150.28
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为产物：
  描述：

  二吡啶并[3,2-a:2',3'-c]吩嗪 、 氢醌-О,О'-二乙酸 、 cadmium(II) hydroxide 以 水 为溶剂， 以45%的产率得到[Cd(dipyrido[3,2-a2',3'-c]phenazine)(benzene-1,2-dioxyacetate)]
  参考文献：
  名称：

  Four metal–organic networks based on benzene-1,4-dioxyacetic acid and dipyrido[3,2-a:2′,3′-c]phenazine ligand

  摘要：

  Four structurally diverse complexes, [Cd(dppz)(bdoa)](n) (1), [Zn(dppz)(bdoa)(H(2)O)](n) (2), [Fe(dppz)(2)(b-doa)](n)center dot 2nH(2)O (3), and [Co(2)(dppz)(2)(bdoa)(2)(H(2)O)](n)center dot 3nH(2)O (4), where H(2)bdoa = benzene-1,4-dioxyacetic acid and dppz = dipyrido[3,2-a:2',3'-c]phenazine, have been hydrothermally synthesized. Compounds 1-4 feature chain structures. There exist pi-pi interactions in the structures of 1, 2 and 4. Two neighboring chains of 1 are linked through the pi-pi interactions into a double chain supramolecular structure. The chains of 2 and 4 are further extended by the pi-pi interactions to form 3D and 2D supramolecular structures, respectively. The structural differences among such complexes show that the transition metals have important influences on their structures. The photoluminescent property of complex 2 and the magnetic property of complex 4 have also been investigated. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.056