(NBu)4Pd(2,6-diphenylpyridine)(CH2COCH3) | 959585-77-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹嗪类
• 英文名称: (NBu)4Pd(2,6-diphenylpyridine)(CH2COCH3)
• CAS: 959585-77-4
• 化学式: C₁₆H₃₆N*C₂₀H₁₆NOPt
• 分子量: 723.902
• InChiKey: PUEGYXPMYWNLIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetra-n-butylammonium hydroxide 、 Pt(ph(py)ph)(DMSO) 、 丙酮 以 甲醇 、 丙酮 为溶剂， 以45%的产率得到(NBu)4Pd(2,6-diphenylpyridine)(CH2COCH3)
  参考文献：
  名称：

  Synthesis, Characterization and Photophysics of a New Series of Anionic C,N,C Cyclometalated Platinum Complexes

  摘要：

  A novel series of anionic mononuclear terdentate dicyclometalated complexes (NBu4)[Pt(C boolean AND N boolean AND C)X] (HC boolean AND N boolean AND CH = 2,6-diphenylpyridine) containing acetylide (X = C CR, R = Bu-t, 1; Ph, 2; Tol, 3; (4-OMe)C6H4, 4) or another anionic ligand (X = CN, 5; S-2Py, 6; CH2COCH3, 7) have been synthesized and fully characterized. The solid-state structures of complexes 1 and 4-6 have also been determined by X-ray diffraction studies, showing, in all the cases, the presence of several types of weak hydrogen interactions, leading to the generation of supramolecular 2D (1) or 3D (4-6) architectures. All the complexes (1-7) are intensely luminescent at low temperature (solid and glassy CH2Cl2), exhibiting concentration dependence in the emissions of the glassy CH2Cl2 matrix.

  DOI：

  10.1021/ic701298z