[Cu(acetate)(OC10H8CHNCH2CH2NHCH2CH2OH)] | 1338696-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Cu(acetate)(OC10H8CHNCH2CH2NHCH2CH2OH)]
• CAS: 1338696-85-7
• 化学式: C₁₇H₂₀CuN₂O₄
• 分子量: 379.903
• InChiKey: FRKZBVJNYUUXRO-HSZLIDMQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) acetate monohydrate 、 (1-{[2-(2-hydroxyethyl amino)ethylimino]methyl}naphthalen-2-ol) 以 甲醇 、 二氯甲烷 为溶剂， 反应 4.0h， 以68%的产率得到[Cu(acetate)(OC10H8CHNCH2CH2NHCH2CH2OH)]
  参考文献：
  名称：

  具有席夫碱配体的过渡金属配合物 1-{[2-(2-Hydroxyethylamino)ethylimino]methyl}naphthalen-2-ol

  摘要：

  六种过渡金属化合物[Cu(H2L)(CH3COO)]·H2O(1)、[Cu(H2L)(CH3COO)](2)、[Cu(H2L)](ClO4)·CH3OH(3)、2[Cu (H2L)2] (4)、[Co(H2L)2](NO3)·2CH3OH (5) 和 [Ni(H2L)](NO3) (6) 通过席夫碱配体 H3L (1 -{[2-(2-羟乙基氨基)乙基亚氨基]甲基}naphthalen-2-ol)与相应的金属盐并通过单晶X射线衍射、元素分析、IR和UV/Vis光谱以及TG分析表征。所有化合物都是单核分子，其中席夫碱配体表现出多种配位模式和构象。N–H…O、O–H…O 和 C–H…O 分子间和分子内氢键相互作用将这些分子连接成多维网络超分子结构。

  DOI：

  10.1002/zaac.201200327

文献信息

• Synthesis, structure, and properties of coordination compounds of copper(II) acetate with substituted 2-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenol
  作者：A. P. Gulya、Yu. M. Chumakov、V. I. Tsapko、V. O. Graur、K. S. Lozan-Tyrshu、E. Janno、B. Ya. Antosyak、V. F. Rudik

  DOI：10.1134/s1070363211090209

  日期：2011.9

  Salicylic, 5-chloro-5-bromo-5-nitro-, 3-methoxysalicylic, 2-hydroxy-1-naphthoic aldehydes and 2,3-, 2,4-, and 2,5-dihydroxybenzaldehyde were shown to react in ethanol with 2-(2-aminoethylamino)ethanol in the presence of copper acetate hydrate forming coordination compounds Cu(L1-9)CH3COO HL1-8, 2-([2-(2-hydroxyethylamino)ethylimino]methyl}phenol (HL1) and respective chloro-(HL2), bromo-(HL3), nitro-(HL4), methoxy- (HL8), or hydroxy-substituted (HL5-7); HL9, 2-[2-(2-hydroxyethylamine)ethylimino]methylnaphthol)}. Structure of the complex Cu(L-3)CH3COO was determined by X-ray diffraction analysis. Coordination polyhedron of its central atom is a distorted tetragonal bipyramid with (4+1+1) modes of coordinating the copper atom. The bipyramid base is formed by the atoms of phenol oxygen and of azomethine and imine nitrogen atoms of the ligand (HL3) and the oxygen atom of the acetate ion. Axial apices of the bipyramid are occupied by the alcohol oxygen atoms of the azomethine (HL3) and the second oxygen atom of the acetate ion. Other complexes are also of monomer structure. Azomethines (HL1-9) behave as mono-deprotonated tetradentate O,N,N,O ligands. The thermolysis of substances includes a stage of complete thermal decomposition (360-530 degrees C). Synthesized complexes show selective antimicrobial activity against a series of standard strains of Staphylococcus aureus and E. coli at the concentration in the range of 75-300 mu g ml(-1). DOI: 10.1134/S1070363211090209