(11Z,13Z,51Z,53Z)-12,13,52,53-tetrahydro-11H,51H-2,4,6,8-tetraaza-1(1,3),5(3,1)-dipyrrolo[3,4-c]pyridina-3,7(2,6)-dipyridinacyclooctaphane | 145183-30-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: (11Z,13Z,51Z,53Z)-12,13,52,53-tetrahydro-11H,51H-2,4,6,8-tetraaza-1(1,3),5(3,1)-dipyrrolo[3,4-c]pyridina-3,7(2,6)-dipyridinacyclooctaphane
• CAS: 145183-30-8
• 化学式: C₂₄H₁₄N₁₀
• 分子量: 442.442
• InChiKey: ILAIHOIYOFXICE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.11
• 重原子数：
  34.0
• 可旋转键数：
  0.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  134.7
• 氢给体数：
  2.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  (11Z,13Z,51Z,53Z)-12,13,52,53-tetrahydro-11H,51H-2,4,6,8-tetraaza-1(1,3),5(3,1)-dipyrrolo[3,4-c]pyridina-3,7(2,6)-dipyridinacyclooctaphane 、 nickel diacetate 以 硝基苯 、 苯甲醇 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  The synthesis of water-soluble hemiporphyrazine analogues

  摘要：

  The synthesis of a new class of water-soluble tetradentate macrocyclic complexes is reported. A hemiporphyrazine derivatized with pyridine groups about the periphery has been prepared. The copper(II) and nickel(II) complexes were synthesized from the free-base ligand. The peripheral pyridine groups of the free ligand and the metal complexes have been methylated to yield complexes exhibiting appreciable water solubility. Visible absorption spectra and cyclic voltammetric data are reported.

  DOI：

  10.1016/s0020-1693(00)84966-x