| 412003-68-0

• CAS: 412003-68-0
• 化学式: C₁₇H₃₂B₁₁N
• 分子量: 369.369
• InChiKey: PHOZJFAZTATNNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis(dimethylamido)titanium(IV) 、 以 甲苯 为溶剂， 以29%的产率得到(η(5)-C2B9H11)Ti(NMe2)2(NHMe2)
  参考文献：
  名称：

  Synthesis, Structural Characterization, and Catalytic Property of Group 4 Metal Carborane Compounds with a ⁱPr₂NB-Bridged Constrained-Geometry Ligand

  摘要：

  Interaction of (Pr2NB)-Pr-i(C9H7)(C2B10H11) with 1 equiv of Zr(NMe2)(4) gave a constrained-geometry zirconium amide [eta(5):sigma-(Pr2NB)-Pr-i(C9H7)(C2B10H11)]Zr(NMe2)(2) (2). Treatment of (Pr2NB)-Pr-i(C9H7)(C2B10H11) with I equiv of Ti(NMe2)(4), however, led to the isolation of a deborated product (eta(5)-C2B9H11)Ti(NMe2)(2)(HNMe2) (1). 2 reacted with excess Me3SiCl in toluene to give the chloro derivative [eta(5):sigma-(Pr2NB)-Pr-i(C9H6)(C2B10H10)]ZrCl2 (4). Salt metathesis reaction between MCl4(THF)(2) and [(Pr2NB)-Pr-i(C9H6)(C2B10H10)]Li-2(Et2O)(2) afforded [eta(5):sigma(-i) Pr2NB(C9H6)(C2B10H10)]-MCl2 (M = Ti (3), Zr (4), Hf (5)). 3 was also prepared from the reaction of [(Pr2NB)-Pr-i(C9H6)-(C2B10H10)]Li-2(Et2O)(2) with 1 equiv of TiCl3(THF)(3), followed by addition of 0.5 equiv of PbCl2 in THF. Interaction of 2 with 4 equiv of Me3Al in toluene resulted in the isolation of [eta(5):sigma-(Pr2NB)-Pr-i(C9H6)(C2B10H10)]ZrMe2 (6). 6 was also prepared via the reaction of 4 with 2 equiv of MeLi in THF. All of these compounds were fully characterized by various spectroscopic data and elemental analyses. The solid-state structures of compounds 1 and 2 were further confirmed by single-crystal X-ray analyses. Compounds 2-6 exhibited a moderate to very high (10(4)-10(6) g mol(-1) atm(-1) h(-1)) ethylene polymerization activity upon activation with MAO. The activities depended upon both the central metal ion and co-ligand and followed the order 4 > 2, 6 > 3 > 5.

  DOI：

  10.1021/om020325j