naphthalene-1,5-diylbis(diethylphosphoramidite) | 244775-41-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: naphthalene-1,5-diylbis(diethylphosphoramidite)
• 英文别名: N-[[5-[bis(diethylamino)phosphanyloxy]naphthalen-1-yl]oxy-(diethylamino)phosphanyl]-N-ethylethanamine
• CAS: 244775-41-5
• 化学式: C₂₆H₄₆N₄O₂P₂
• 分子量: 508.624
• InChiKey: UZIZUHJTIGSMGD-UHFFFAOYSA-N

物化性质

• 沸点：
  555.6±60.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  34
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  31.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  naphthalene-1,5-diylbis(diethylphosphoramidite) 在 sulfur 作用下， 以 乙腈 、 苯 为溶剂， 生成 3,16-(diethylamino)-2,4,15,17-tetraoxa-3,16-diphosphapentacyclo[20.4.0.0^5,10.0^9,14.0^18,23]hexacosa-1(22),5(10),6,8,11,13,18,20,23,25-decaene-3,16-dithione
  参考文献：
  名称：

  Rasadkina; Nifant'ev, Russian Journal of General Chemistry, 1999, vol. 69, # 3, p. 489 - 490

  摘要：

  DOI：
• 作为产物：
  描述：

  1,5-二羟基萘 、 六乙基亚磷酸胺 以 乙腈 为溶剂， 生成 naphthalene-1,5-diylbis(diethylphosphoramidite)
  参考文献：
  名称：

  Nifantiev, Edward E., Phosphorus, Sulfur and Silicon and the Related Elements, 1999, vol. 144, p. 343 - 346

  摘要：

  DOI：

文献信息

• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• ——
  作者：E. E. Nifant'ev、E. N. Rasadkina、Yu. B. Evdokimenkova、L. K. Vasyanina、A. I. Stash、V. K. Bel'skii

  DOI：10.1023/a:1012378817167

  日期：——

  1,5- and 2,7-dihydroxynaphthalenes were reacted with P(III) amides to obtain naphthocyclophanes. The structures and chemical properties of the products were studied.