| 355119-66-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 355119-66-3
• 化学式: C₄₂H₄₂CuN₄O₈
• 分子量: 794.363
• InChiKey: LUMJGLBRVNSTGX-CEXFFYCFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙醇 、 (2R)-2-hydroxy-N-[(2-hydroxynaphthalen-1-yl)methylideneamino]-2-phenylacetamide 、 copper diacetate 以 乙醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF NEW Cu(II) COMPLEXES DERIVED FROM BENZILIC AND MANDELIC HYDRAZONES

  摘要：

  Two new sets of Cu(II) complexes with newly synthesised benzilic and mandelic hydrazone derivatives were prepared in the mole ratios 1:1 and 1:2 (Cu:L). The structure of the complexes was identified on the basis of the data obtained from elemental and thermal analyses as well as IR, UV-visible, ESR spectra, and X-ray diffraction. The results indicate that the ligands are tightly bound to the metal ion through the phenolic OH oxygen, the azomethine nitrogen, and the enolic OH oxygen in case of the 1:1 complexes while for the 1:2 complexes the enolic OH group did not participate in bonding. The complexes have elongated octahedral as well as square-planar symmetries.[GRAPHICS]

  DOI：

  10.1081/sim-100001935