N-propyl-N'-phenyl-p-phenylenediamine | 10194-09-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-propyl-N'-phenyl-p-phenylenediamine
• 英文别名: N-phenyl-N'-propyl-p-phenylenediamine；4-N-phenyl-1-N-propylbenzene-1,4-diamine
• CAS: 10194-09-9
• 化学式: C₁₅H₁₈N₂
• 分子量: 226.321
• InChiKey: PILIQRYPQJIREQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Direct alkylation of N-alkyl-N'-phenyl-p-phenylenediamine
  申请人：Wang Jin-Yun

  公开号：US20070173668A1

  公开（公告）日：2007-07-26

  A single-step process is disclosed for the ring alkylation of at least one N-alkyl-N′-phenyl-phenylenediamine with at least one olefin wherein the process comprises heating a mixture of the N-alkyl-N′-phenyl-phenylenediamine(s) and olefin(s) in the presence of a catalytic amount of at least one alkyl aluminum halide at a temperature of from about 50 to about 350° C. in a sealed vessel for from about one to about 30 hours.

  揭示了一种单步过程，用于将至少一种N-烷基-N'-苯基-苯二胺与至少一种烯烃进行环烷化反应，其中该过程包括在密封容器中，在存在至少一种烷基铝卤化物的催化剂作用下，将N-烷基-N'-苯基-苯二胺(s)和烯烃(s)的混合物加热至约50℃至约350℃的温度，反应时间为约1至约30小时。
• METHOD FOR PRODUCING N-ISOPROPYL(METH)ACRYLAMIDE
  申请人：Knebel Joachim

  公开号：US20110218312A1

  公开（公告）日：2011-09-08

  A novel process is described which allows N-isopropyl(meth)acrylamide to be obtained in high purity and yield in a simple manner, by reacting methacrylic anhydride with isopropylamine, optionally in a solvent.

  本文描述了一种新的工艺，通过将甲基丙烯酸酐与异丙胺反应，可在高纯度和高收率的情况下简单地获得N-异丙基（甲基）丙烯酰胺，可选地在溶剂中进行反应。
• Rubber-like polymers for tire treads, a process for their preparation, and compositions containing said polymers
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP0252992A1

  公开（公告）日：1988-01-20

  Rubbery polybutadiene or rubbery butadiene-styrene copolymer suited for a tire tread, which is obtained by polymerization in the presence of an organolithium catalyst and reacting the active living site with a carbodiimide and, If necessary, a tri-functional or higher functional coupling agent. Process for its production and composition containing it in an amount above a predetermined level are also disclosed.

  适用于轮胎胎面的橡胶聚丁二烯或橡胶丁二烯-苯乙烯共聚物，在有机锂催化剂存在下通过聚合反应获得，其活性活部位与碳化二亚胺反应，必要时与三官能或更高官能偶联剂反应。此外，还公开了其生产工艺和含量超过预定水平的组合物。
• Method and composition for inhibiting acrylate ester polymerization
  申请人：BETZ EUROPE, INC.

  公开号：EP0266906A2

  公开（公告）日：1988-05-11

  Compositions and methods of inhibiting acrylate monomer polymerization at elevated temperatures comprising adding to the acrylate monomer an effective amount for the purpose of (a) hydroxylamine having the formula wherein R and Rʹ are the same or different and are hydrogen, or straight or branched chain alkyl, aryl, alkaryl or aralkyl groups,and (b) a para-phenylenediamine or derivative thereof having at least one N-H group.

  在高温下抑制丙烯酸酯单体聚合的组合物和方法，包括向丙烯酸酯单体中加入有效量的 (a) 羟胺，其式为 其中R和Rʹ相同或不同，并且是氢、或直链或支链烷基、芳基、烷芳基或芳烷基，和 (b) 对苯二胺或其衍生物，至少有一个N-H基团。
• Hydroxyether-carboxylic acids and lactones thereof, process for their production and their use as corrosion inhibitors
  申请人：CIBA-GEIGY AG

  公开号：EP0302007A1

  公开（公告）日：1989-02-01

  A composition, in contact with a corrodable metal surface, comprising: a) an aqueous-based or oil-based system; and b) as an inhibitor for protecting the metal surface against corrosion, at least one compound having the formula I or II: in which R is C₄-C₂₀alkyl, C₄-C₂₀alkyl interrupted by one or more oxygen atoms, C₄-C₂₀alkenyl, C₆-C₁₀aryl, C₇-C₁₅alkaryl, C₇-C₁₅aralkyl or C₅-C₁₂cyclo­alkyl; R¹, R² and R³ are the same or different and each is methyl or, preferably, hydrogen; M is hydrogen, a metal ion, ammonium or substituted ammonium ion; a is 0 or 1; b is 0 or an integer from 1 to 6, preferably 0, 1, 2 or 3 especially 0 or 1; and c is an integer from 1 to 6; and/or at least one compound having the formula II: in which R, R³ and a are as defined above.

  一种与易腐蚀金属表面接触的组合物，包括 a) 水性或油性体系；以及 b) 至少一种具有式 I 或式 II 的化合物，作为保护金属表面免受腐蚀的抑制剂： 其中 R 是 C₄-C₂₀ 烷基、被一个或多个氧原子间断的 C₄-C₂₀ 烷基、C₄-C₂₀ 烯基、C₆-C₁₀芳基、C₇-C₁₅ 芳烷基、C₇-C₁₅ 芳烷基或 C₅-C₁₂cylo 烷基； R¹、R² 和 R³ 既可以相同，也可以不同，并且各自是甲基，最好是氢； M 是氢、金属离子、铵或取代的铵离子； a 是 0 或 1； b 是 0 或 1 到 6 的整数，最好是 0、1、2 或 3，特别是 0 或 1；以及 c 是 1 至 6 的整数；和/或至少一种化合物具有式 II： 其中 R、R³ 和 a 如上定义。