3-(naphthalen-1-yl)isoquinoline | 1180487-27-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 3-(naphthalen-1-yl)isoquinoline
• 英文别名: 3-Naphthalen-1-ylisoquinoline
• CAS: 1180487-27-7
• 化学式: C₁₉H₁₃N
• 分子量: 255.319
• InChiKey: YTTYNMGFPQYWKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(萘-1-基甲基)异吲哚-1,3-二酮 在 甲基二乙氧基硅烷 、 potassium trimethylsilonate 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 6.0h， 以46%的产率得到3-(naphthalen-1-yl)isoquinoline
  参考文献：
  名称：

  通过串联还原和重排的醇酰亚胺催化的环状酰亚胺氢化成异喹啉

  摘要：

  通过串联还原和重排实现了醇盐催化的环状酰亚胺氢化成异喹啉。使用TMSOK作为催化剂，使用（EtO）2 MeSiH作为还原剂，将一系列包含不同官能团的环状酰亚胺以中等至良好的产率还原为相应的3-芳基异喹啉。该反应途径的场景被认为包括将酰亚胺还原为ω-羟基内酰胺，其在碱性催化剂的存在下进行重排，然后羰基还原，然后甲硅烷氧基消除。

  DOI：

  10.1021/acs.orglett.8b02287

文献信息

• NOVEL ORGANIC HETEROCYCLIC COMPOUND AND LIGHT-EMITTING DEVICE COMPRISING SAME
  申请人：SFC CO., LTD.

  公开号：US20180072753A1

  公开（公告）日：2018-03-15

  The present invention relates to an organic light-emitting compound represented by [Chemical Formula A] and an organic light-emitting device. In Chemical Formula, A, X, Y, Z, and the substituents R 1 to R 8 , and R 11 to R 20 are as defined in the specification.

  本发明涉及一种由[化学公式A]表示的有机发光化合物以及一种有机发光器件。在化学公式中，A、X、Y、Z以及取代基R1至R8和R11至R20如说明书中所定义。
• METHOD FOR PRODUCING CYCLOMETALATED IRIDIUM COMPLEX
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US20180362565A1

  公开（公告）日：2018-12-20

  The present invention provides a method for producing a cyclometalated iridium complex by use of a non-chlorine iridium raw material. The method for producing a cyclometalated iridium complex includes producing a cyclometalated iridium complex by reacting a raw material including an iridium compound with an aromatic heterocyclic bidentate ligand capable of forming an iridium-carbon bond, the raw material being non-halogenated iridium having a conjugated base of a strong acid as a ligand. Here, the non-halogenated iridium is preferably one containing a conjugated base of a strong acid having a pKa of 3 or less as a ligand.

  本发明提供了一种利用非氯化铱原料生产环金属化铱配合物的方法。生产环金属化铱配合物的方法包括通过将包含铱化合物的原料与能够形成铱-碳键的芳香杂环双齿配体反应来生产环金属化铱配合物，所述原料是非卤化铱，其具有强酸的共轭碱作为配体。在这里，非卤化铱最好是含有pKa值为3或更低的强酸的共轭碱作为配体的铱。
• RAW MATERIAL AND PRODUCTION METHOD FOR CYCLOMETALLIZED IRIDIUM COMPLEX
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US20160326198A1

  公开（公告）日：2016-11-10

  The present invention relates to a raw material for a cyclometalated iridium complex, and provides a technique that makes it possible to obtain a cyclometalated iridium complex in higher yield at a lower reaction temperature than using tris(2,4-pentanedionato)iridium(III). The present invention relates to a raw material for a cyclometalated iridium complex, including an organic iridium material for producing a cyclometalated iridium complex, the organic iridium material being a tris(β-diketonato)iridium(III), in which an asymmetric β-diketone is coordinated to iridium.

  本发明涉及一种用于环金属铱配合物的原料，并提供了一种技术，使得能够在比使用三(2,4-戊二酮)铱(III)更低的反应温度下以更高收率获得环金属铱配合物。本发明涉及一种用于环金属铱配合物的原料，包括用于生产环金属铱配合物的有机铱材料，该有机铱材料为三(β-二酮酸盐)铱(III)，其中一个不对称的β-二酮酸盐与铱配位。
• A Dramatic Substituent Effect in Silver(I)-Catalyzed Regioselective Cyclization of ortho-Alkynylaryl Aldehyde Oxime Derivatives
  作者：Hongyin Gao、Junliang Zhang

  DOI：10.1002/adsc.200800568

  日期：2009.1

  A dramatic substituent effect was found in the silver(I)-catalyzed cyclization reaction of ortho-alkynylaryl aldehyde oxime derivatives. When R is an alkyl group, the Ag(I)-catalyzed reaction in dimethylacetamide at 110 °C (conditions A) affords isoquinolines in good to excellent yields, in contrast, isoquinolin-1(2 H)-ones were produced in moderate to high yields under conditions B (dimethylformamide

  在邻炔基芳基醛肟肟衍生物的银（I）催化的环化反应中发现了显着的取代作用。当R为烷基时，在110°C（条件A）下在二甲基乙酰胺中的Ag（I）催化反应以良好至极好的收率得到异喹啉，相反，异喹啉-1（2  H）-以中等至当R为乙酰基时，在条件B（二甲基甲酰胺，室温）下高收率。通过细微的结构修饰，为该产物选择性控制反应（PSCR）提出了合理的机制。
• METAL COORDINATION COMPOUND AND LIGHT-EMITTING MATERIAL CONTAINING THE SAME
  申请人：Konno Hideo

  公开号：US20100317858A1

  公开（公告）日：2010-12-16

  To provide a light-emitting device that is capable of red-light-emitting with high luminance and high efficiency and that is excellent in endurance; and a metal coordination compound metal coordination compound having a partial structure represented by formula (1) that can be used in the light-emitting device, and that can also be used in applications, such as organic electroluminescent device materials, electrochemiluminescence (ECL) device materials, emission sensors, photosensitizers, displays, photographic materials, laser dyes, color filter dyes, optical communications, color conversion filters, backlights, illuminations, photosensitizing dyes, various light sources, and the like.

  提供一种具有高亮度和高效率的红光发射能力、并且具有出色耐久性的发光装置；以及具有由公式（1）表示的部分结构的金属配位化合物，可用于发光装置中，并可用于有机电致发光器件材料、电化学发光（ECL）器件材料、发射传感器、光敏剂、显示器、摄影材料、激光染料、彩色滤光片染料、光通信、色彩转换滤光片、背光、照明、光敏染料、各种光源等应用中。