bibenzyl; compound with antimony trichloride | 57982-87-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: bibenzyl; compound with antimony trichloride
• 英文别名: Bibenzyl; Verbindung mit Antimontrichlorid
• CAS: 57982-87-3；57982-88-4
• 化学式: C₁₄H₁₄*2Cl₃Sb
• 分子量: 638.483
• InChiKey: NRSXBKXVHJFQIU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  5.16
• 重原子数：
  18.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  三氯化锑 、 1,2-二苯乙烷 以 正己烷 、 二氯甲烷 为溶剂， 以92%的产率得到bibenzyl; compound with antimony trichloride
  参考文献：
  名称：

  Tethered Diarenes as Four-Site Donors to SbCl₃

  摘要：

  Three complexes of the general form [SbCl3](4) .[Ph-Ph] ([Ph-Ph] = bibenzyl, trans-stilbene, or diphenylacetylene) have been isolated in high yield as crystalline solids. The characteristics of the new materials significantly differ from those of the precursors, and their solid state structures have been determined by X-ray crystallography. The pi-complexes are isotypical with each other and with the previously reported [SbCl3](2) .[benzene] complex. On this basis and in comparison with related systems, the factors governing the structure of SbCl3-arene complexes are discussed.

  DOI：

  10.1021/om950561c