(R)-N,N,N',N'-tetraphenyl-1,1'-binaphthyl-2,2'-diamine | 697766-36-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (R)-N,N,N',N'-tetraphenyl-1,1'-binaphthyl-2,2'-diamine
• 英文别名: N,N-diphenyl-1-[2-(N-phenylanilino)naphthalen-1-yl]naphthalen-2-amine
• CAS: 697766-36-2；1048378-07-9
• 化学式: C₄₄H₃₂N₂
• 分子量: 588.751
• InChiKey: ZXBBAMSYURBXPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.5
• 重原子数：
  46
• 可旋转键数：
  7
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 、 (R)-N,N,N',N'-tetraphenyl-1,1'-binaphthyl-2,2'-diamine 、 水 以 乙醚 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis of Optically Active N,N,N′,N′-Tetraphenyl-1,1′-binaphthyl-2,2′-diamine Derivatives as Analogues of BINAP

  摘要：

  As analogues of BINAP, optically active N,N,N',N'-tetraaryl-1,1'-binaphthyl-2,2'-diamines have been prepared by palladium-catalyzed coupling reactions of optically active 1,1'-binaphthyl-2,2'-diamine with an excess amount of aryl bromides. A novel diamine-bridged dirhodium T-arene complex has been produced and characterized by X-ray analysis.

  DOI：

  10.1021/om800485s

文献信息

• Compound, Organic Electroluminescent Device Containing Same and Application Thereof
  申请人：BEIJING ETERNAL MATERIAL TECHNOLOGY CO., LTD

  公开号：US20220158095A1

  公开（公告）日：2022-05-19

  A compound, an organic electroluminescent device containing the compound, and an application thereof. The compound has a structure shown in (I).
• Synthesis of Optically Active <i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-Tetraphenyl-1,1′-binaphthyl-2,2′-diamine Derivatives as Analogues of BINAP
  作者：Hiroshi Matsuzawa、Yoshiaki Tanabe、Yoshihiro Miyake、Yoshiaki Nishibayashi

  DOI：10.1021/om800485s

  日期：2008.8.1

  As analogues of BINAP, optically active N,N,N',N'-tetraaryl-1,1'-binaphthyl-2,2'-diamines have been prepared by palladium-catalyzed coupling reactions of optically active 1,1'-binaphthyl-2,2'-diamine with an excess amount of aryl bromides. A novel diamine-bridged dirhodium T-arene complex has been produced and characterized by X-ray analysis.