2-morpholino-4,6-bis(normal butylamino)-1,3,5-triazine | 174300-87-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-morpholino-4,6-bis(normal butylamino)-1,3,5-triazine
• 英文别名: 2-morpholino-4,6-bis(n-butylamino)-1,3,5-triazine；2-N,4-N-dibutyl-6-morpholin-4-yl-1,3,5-triazine-2,4-diamine
• CAS: 174300-87-9
• 化学式: C₁₅H₂₈N₆O
• 分子量: 308.427
• InChiKey: GDXGOYXZDUUYSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  75.2
• 氢给体数：
  2
• 氢受体数：
  7

文献信息

• PROTON-CONDUCTING COMPOUND AND PROTON-CONDUCTING POLYMER
  申请人：Kawada Atsushi

  公开号：US20100063249A1

  公开（公告）日：2010-03-11

  Provided is a proton-conducting compound which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. Provided also is a proton-conducting polymer. The proton-conducting compound is composed of a melamine compound salt obtained from a melamine compound represented by the following formula (1) and a Bronsted acid and the proton-conducting polymer is obtained by homopolymerizing or copolymerizing the melamine compound salt. In formula (1), R 1 , R 2 , R 3 , R 4 , and R 5 each is independently an alkyl group, an aryl group, an alkenyl group, a heterocyclic group, or a hydrogen atom; at least one of them is a group other than hydrogen; R 2 and R 3 or R 4 and R 5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, the alkenyl group, or the heterocyclic group may have a substituent. A melamine compound salt wherein R 1 is CH 2 ═CR 6 —CO—O(CH 2 ) n — polymerizes to yield a proton-conducting polymer. In this particular R 1 group, R 6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1.

  提供了一种质子导电化合物，它能在不加湿的情况下提供质子导电性，适用于固体电解质燃料电池和电池电解质等电化学器件材料。还提供了一种质子导电聚合物。该质子导电化合物由以下式（1）所表示的三聚氰胺化合物盐和布朗斯特酸组成，而质子导电聚合物则是通过同聚或共聚三聚氰胺化合物盐得到的。在式（1）中，R1、R2、R3、R4和R5各自独立地表示烷基、芳基、烯基、杂环基或氢原子；其中至少一个是除氢以外的基团；R2和R3或R4和R5可结合形成杂环结构；而烷基、芳基、烯基或杂环基上可能有取代基。其中，R1为CH2═CR6—CO—O( )n—的三聚氰胺化合物盐聚合后可得到质子导电聚合物。在这种特定的R1基团中，R6为氢或烷基，n为大于等于1的整数。
• PROCESS FOR ALKYLATING TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0760369A1

  公开（公告）日：1997-03-05

  The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.

  本发明的目的是提供一种高产率生产取代的-1,3,5-三嗪衍生物的方法，在这种衍生物中，其环上至少有一个碳原子被至少有一个烷基的仲胺基取代。 本发明的方法是 1,3,5-三嗪衍生物的烷基化方法，其特征是将 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）与至少具有一个或多个烷基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）反应。其特征是：在元素周期表中第 VII 族和/或 VIII 族金属和含氢气体催化剂的存在下，将环的碳原子上至少有一个或多个氨基或单取代氨基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种鸟苷酸衍生物等）与醛或酮醇反应，使上述至少一个氨基或单取代氨基烷基化。 这些衍生物被广泛用作精细化工产品的中间体，如农药、药物、染料、油漆等，也被广泛用作树脂材料和阻燃材料。
• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。
• US6124381A
  申请人：——

  公开号：US6124381A

  公开（公告）日：2000-09-26
• US6130332A
  申请人：——

  公开号：US6130332A

  公开（公告）日：2000-10-10