Cu(2-oxy-3-(3-methyl-2-butenyl)-1,4-naphthoquinone)2(pyridine)2 | 959772-41-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Cu(2-oxy-3-(3-methyl-2-butenyl)-1,4-naphthoquinone)2(pyridine)2
• 英文别名: Cu(lapachol-H)2(pyridine)2
• CAS: 959772-41-9
• 化学式: C₄₀H₃₆CuN₂O₆
• 分子量: 704.282
• InChiKey: YGXLMRLTLLYLFB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 黄钟花醌 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 以81%的产率得到Cu(2-oxy-3-(3-methyl-2-butenyl)-1,4-naphthoquinone)2(pyridine)2
  参考文献：
  名称：

  Complexes of Co(II), Ni(II) and Cu(II) with lapachol

  摘要：

  Complexes of naturally occurring hydroxynaphtho-quinone, lapachol (2-hydroxy-3(3-methyl-2-buthenyl)-1,4-naphthoquinone = HL) with Co(II), Ni(II) and Cu(II) have been prepared by reaction of the corresponding acetates with the ligand (HL) in ethanol. The molecular and crystal structures were determined for [CoL2(EtOH)(2)] (1), [NiL2(EtOH)(2)] (2), and [CuL2(py)(2)] (3). In all cases the deprotonated lapachol behaves as chelating bidentate ligand. The complexes were also characterized by elemental analyses, cyclic voltammetry, and FAB-MS. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.06.022