tris-(4'-carbazol-9-yl-biphenyl-4-yl)-amine | 207447-34-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris-(4'-carbazol-9-yl-biphenyl-4-yl)-amine
• 英文别名: 4-(4-carbazol-9-ylphenyl)-N,N-bis[4-(4-carbazol-9-ylphenyl)phenyl]aniline
• CAS: 207447-34-5
• 化学式: C₇₂H₄₈N₄
• 分子量: 969.2
• InChiKey: LHLOSFZDKSCBIC-UHFFFAOYSA-N

物化性质

• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  19.3
• 重原子数：
  76
• 可旋转键数：
  9
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-[4-(4,4,5,5-四甲基-1,3,2-二氧硼杂环戊烷-2-基)苯基]-9H-咔唑 在 Pd(PPh3)4 potassium carbonate 作用下， 以 1,4-二氧六环 、 水 为溶剂， 生成 tris-(4'-carbazol-9-yl-biphenyl-4-yl)-amine
  参考文献：
  名称：

  Cross Linked Organic Conductive Layer

  摘要：

  本发明提供了各种化合物、组合物、方法和过程，用于在电子设备中形成交联导电聚合层。

  公开号：

  US20110245429A1

文献信息

• Starburst dendrimers consisting of triphenylamine core and 9-phenylcarbazole-based dendrons: synthesis and properties
  作者：Jia You、Guiyang Li、Zhonggang Wang

  DOI：10.1039/c2ob26483h

  日期：——

  the dendrons in dendrimers greatly twisted with the generation, leading to the dendrimers decreased crystalline ability. Of interest is the observation that, for an identical dendrimer, the solid film displays the similar UV absorption and luminescence emission profiles to the solution sample, indicating that, after evaporation of solvent, the rigid dendrimer can well maintain its conformational morphology

  通过收敛的Suzuki偶联反应，合成了由三苯胺核和第一至第三代9-苯基咔唑基树枝状分子组成的新型树枝状聚合物。二维相关的H–H COZY和C–H HSQC NMR光谱，MALDI-TOF MS和元素分析证实了它们的结构。树枝状聚合物具有出色的热稳定性，在540°C范围内失重温度为5％。计算机建模表明，树枝状聚合物中的树枝状分子随着世代的发生而大大扭曲，从而导致树枝状聚合物的结晶能力降低。有趣的是，对于相同的树枝状聚合物，固体膜显示出与溶液样品相似的UV吸收和发光发射曲线，这表明在蒸发溶剂后，刚性树枝状聚合物可以很好地保持其构象形态，发色基团的聚集或堆积被显着抑制。所有的树枝状分子都可以发出强烈的荧光，其窄的半峰全宽（FWHM）约为46–50 nm。此外，随着生成的增加，量子效率从64％显着提高到95％，这表明高度扭曲且笨重的树枝状结构有效地减少了能量浪费和非辐射衰减。给电子三苯胺核和9-苯
• Amine-based compound and organic light-emitting device including the same
  申请人：Samsung Display Co., Ltd.

  公开号：US10170706B2

  公开（公告）日：2019-01-01

  According to one or more embodiments of the present invention, an amine-based compound is represented by Formula 1 below:

  根据本发明的一个或多个实施例，胺基化合物由下式 1 表示：
• Organometallic complex and organic light-emitting diode including the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10367155B2

  公开（公告）日：2019-07-30

  An organometallic complex and an organic light-emitting diode including the same, the organometallic complex being represented by Formula 1 below:

  一种有机金属络合物和一种包括有机金属络合物的有机发光二极管，有机金属络合物用下式 1 表示：
• ORGANIC ELECTROLUMINESCENT DEVICE AND DISPLAY APPARATUS
  申请人：Matsunami Shigeyuki

  公开号：US20080164809A1

  公开（公告）日：2008-07-10

  An organic electroluminescent device for emitting red light is disclosed. The device includes: an anode; a cathode; and an organic layer including a light-emitting layer, wherein the light-emitting layer contains a red light-emitting guest material and a host material composed of a polycyclic aromatic hydrocarbon compound having a skeleton with 4 to 7 membered rings, and a photosensitizing layer containing a light-emitting guest material generating green light is provided adjacent to the light-emitting layer.
• ORGANIC EL DISPLAY UNIT, METHOD OF MANUFACTURING THE SAME, AND SOLUTION USED IN METHOD
  申请人：Matsumoto Toshiki

  公开号：US20110248247A1

  公开（公告）日：2011-10-13

  An organic electroluminescence display unit includes: a lower electrode for each device; a first hole injection/transport layer provided on the lower electrode for each device; a second organic light emitting layer of the first color provided on the first hole injection/transport layer for the second organic electroluminescence device; a second hole injection/transport layer provided on the entire surfaces of the second organic light emitting layer and the first hole injection/transport layer for the first organic electroluminescence device, and being made of a low molecular material; a blue first organic light emitting layer provided on the entire surface of the second hole injection/transport layer; and an electron injection/transport layer having at least one of electron injection characteristics and electron transport characteristics, and an upper electrode that are provided in sequence on the entire surface of first organic light emitting layer.