Zinc perfluorohexanesulfinate | 86525-30-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 亚磺酸及其衍生物
• 英文名称: Zinc perfluorohexanesulfinate
• 英文别名: zinc;1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfinate
• CAS: 86525-30-6
• 化学式: C12F26O4S2Zn
• 分子量: 831.6
• InChiKey: FERFSNBXEOUUGP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.12
• 重原子数：
  45
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  119
• 氢给体数：
  0
• 氢受体数：
  32

文献信息

• METHOD FOR PRODUCING 2-AMINO-4-SUBSTITUTED PHENOL
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20180282267A1

  公开（公告）日：2018-10-04

  A compound represented by formula (3): (wherein R 1 represents a C1-C6 alkyl group optionally having one or more halogen atoms, R 2 represents a C1-C6 alkyl group, and m represents an integer of 0 to 3) can be produced by reacting a C1-C6 alkanesulfinic acid salt optionally having one or more halogen atoms with a compound represented by formula (2): (wherein R 2 and m are as defined above) in the presence of a protonic acid.

  通过在质子酸存在下，将具有一个或多个卤素原子的C1-C6烷磺酸盐与下式所示的化合物（其中R1表示一个C1-C6烷基基团，可选地具有一个或多个卤素原子，R2表示一个C1-C6烷基基团，m表示0到3的整数）反应，可以制备出一种由式（3）表示的化合物：
• METHOD FOR PRODUCING PERFLUOROALKANESULFONYL PHENOL COMPOUNDS
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20180290970A1

  公开（公告）日：2018-10-11

  A compound represented by formula (3): (wherein R 1 represents a C1-C6 perfluoroalkyl group, R 2 represents a C1-C6 alkyl group, and m represents an integer of 0 to 3) or a salt thereof, which is useful as a production intermediate of pharmaceuticals and agrochemicals, can be produced by reacting an alkali metal salt or zinc salt of a C1-C6 perfluoroalkanesulfinic acid with 2-aminophenol optionally substituted by 1 to 3 C1-C6 alkyl groups or a salt thereof in the presence of an oxidizing agent.

  公式（3）所代表的化合物：（其中R1代表C1-C6全氟烷基基团，R2代表C1-C6烷基基团，m代表0到3的整数）或其盐，可作为制药和农药的生产中间体，通过在氧化剂存在下，将C1-C6全氟烷烯磺酸的碱金属盐或锌盐与1至3个C1-C6烷基基团取代的2-氨基酚或其盐反应而制备。
• Method for producing 2-amino-4-substituted phenol
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US10093617B1

  公开（公告）日：2018-10-09

  A compound represented by formula (3): (wherein R1 represents a C1-C6 alkyl group optionally having one or more halogen atoms, R2 represents a C1-C6 alkyl group, and m represents an integer of 0 to 3) can be produced by reacting a C1-C6 alkanesulfinic acid salt optionally having one or more halogen atoms with a compound represented by formula (2): (wherein R2 and m are as defined above) in the presence of a protonic acid.

  式 (3) 所代表的化合物： (其中 R1 代表任选具有一个或多个卤素原子的 C1-C6 烷基，R2 代表 C1-C6 烷基，m 代表 0 至 3 的整数）。 可通过将任选具有一个或多个卤素原子的 C1-C6 烷基亚硫酸盐与式 (2) 所代表的化合物反应制得： (其中 R2 和 m 如上文所定义） 在质子酸存在下。
• Method for producing perfluoroalkanesulfonyl phenol compounds
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US10160722B2

  公开（公告）日：2018-12-25

  A compound represented by formula (3): (wherein R1 represents a C1-C6 perfluoroalkyl group, R2 represents a C1-C6 alkyl group, and m represents an integer of 0 to 3) or a salt thereof, which is useful as a production intermediate of pharmaceuticals and agrochemicals, can be produced by reacting an alkali metal salt or zinc salt of a C1-C6 perfluoroalkanesulfinic acid with 2-aminophenol optionally substituted by 1 to 3 C1-C6 alkyl groups or a salt thereof in the presence of an oxidizing agent.

  式 (3) 所代表的化合物： (其中，R1 代表 C1-C6 全氟烷基，R2 代表 C1-C6 烷基，m 代表 0 至 3 的整数） 的碱金属盐或锌盐与任选被 1 至 3 个 C1-C6 烷基取代的 2-氨基苯酚或其盐在氧化剂存在下反应，可制得可用作医药和农用化学品生产中间体的 C1-C6 全氟烷基亚磺酸或其盐。