acrylic acid 2-ethoxycarbonyloxy-ethyl ester | 17650-45-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: acrylic acid 2-ethoxycarbonyloxy-ethyl ester
• 英文别名: 2-Ethoxycarbonyloxyethyl prop-2-enoate
• CAS: 17650-45-2
• 化学式: C₈H₁₂O₅
• 分子量: 188.18
• InChiKey: LDWDTBYHGHIJHU-UHFFFAOYSA-N

物化性质

• 沸点：
  88-90 °C(Press: 3 Torr)
• 密度：
  1.113±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  氯甲酸乙酯 、 丙烯酸羟乙酯 生成 acrylic acid 2-ethoxycarbonyloxy-ethyl ester
  参考文献：
  名称：

  快速单体：影响光引发丙烯酸酯聚合中丙烯酸酯单体固有反应性的因素

  摘要：

  对分子结构对丙烯酸酯光引发聚合反应的影响进行了系统的研究。最初，研究的重点是氢键的作用，发现通过氢键进行的预组织可提高最大聚合速率（R p）。这种氢键促进的预组织也影响了所得聚合物的立构规整度。接下来，研究了由给定单体的计算偶极矩（μcalc）表示的极性影响。观察到R p与计算的玻尔兹曼平均偶极矩（μcalc）之间存在直接的线性关系。的[R p -μ计算值相关性适用于纯单体，单体混合物，甚至单体与惰性溶剂的混合物。这种相关性使得能够合理设计具有所需反应性的单体。另外，这些研究表明，聚合的传播步骤受氢键的影响，而偶极矩则影响终止速率常数。可以将这两种机理解释视为影响丙烯酸酯聚合速度的互补因素。

  DOI：

  10.1021/ma021785r

文献信息

• GEL-FORM SOLID POLYMER ELECTROLYTE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0896340A1

  公开（公告）日：1999-02-10

  A polymeric gel electrolyte comprising: (a) an acrylic ester polymer matrix containing structural units derived from at least one acrylic ester selected from among acrylic esters represented by the general formulae: (wherein, in the formula (I), R1, R2 and R2' are identical with or different from each other and represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R3 represents an alkyl group having 1 to 4 carbon atoms, and n is an integer of 1 to 100; and, in the formula (II), R4 to R9 are identical with or different from each other and represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and p, q and r are identical with or different from each other and are an integer of 1 to 100); (b) a nonaqueous solvent of a carbonic ester; and (c) a salt of a metal of Group Ia of the periodic table. This polymeric gel electrolyte uses an acrylic ester polymer as a polymeric matrix and contains a specified nonaqueous solvent, so that it exhibits high ionic conductivity and is electrochemically stable. Thus, the polymeric gel electrolyte can suitably be used in electrochemical devices such as a primary battery, a secondary battery, a capacitor and an electrochromic display and in medical actuators.

  聚合物凝胶电解质，包括 (a) 一种丙烯酸酯聚合物基体，含有至少一种丙烯酸酯衍生的结构单元，该丙烯 酸酯选自通式如下的丙烯酸酯： (其中，在式(I)中，R1、R2 和 R2'彼此相同或不同，代表氢原子或具有 1 至 4 个碳原子的烷基，R3 代表具有 1 至 4 个碳原子的烷基，n 是 1 至 100 的整数；在式（II）中，R4 至 R9 彼此相同或不同，且代表氢原子或具有 1 至 4 个碳原子的烷基，p、q 和 r 彼此相同或不同，且为 1 至 100 的整数）；（b）碳酸酯的非水溶剂；以及（c）元素周期表 Ia 族金属的盐。这种聚合物凝胶电解质使用丙烯酸酯聚合物作为聚合物基质，并含有特定的非水溶剂，因此具有高离子导电性和电化学稳定性。因此，这种聚合物凝胶电解质可适用于电化学装置，如一次电池、二次电池、电容器和电致变色显示器以及医疗致动器。
• Oxime Compound and Resist Composition Containing the Same
  申请人：MASUYAMA Tatsuro

  公开号：US20100021847A1

  公开（公告）日：2010-01-28

  An oxime compound represented by the formula (I): wherein Y represents an unsubstituted or substituted n-valent C6-C14 aromatic hydrocarbon group, n represents an integer of 1 to 6, R 1 ) represents a C1-C30 aliphatic hydrocarbon group etc., R 2 represents a linear or branched chain C1-C20 aliphatic hydrocarbon group etc., W represents —CO—O— etc., Q 1 and Q 2 each independently represent a fluorine atom etc., Z represents a C1-C20 halogenated aliphatic hydrocarbon group etc, and the resist composition containing the same.
• MICROPARTICLE COMPRISING CROSS-LINKED POLYMER
  申请人：Dias Aylvin Jorge Angelo Athanasius

  公开号：US20100291116A1

  公开（公告）日：2010-11-18

  Microparticle comprising a cross-linked polymer comprising (a) a cross-linker comprising two or more radically polymerizable groups, preferably selected from the group consisting of alkenes, sulfhydryl (SH), thioic, unsaturated esters, unsaturated urethanes, unsaturated ethers, and unsaturated amides; (b) a monofunctional reactive diluent comprising maximum one unsaturated C—C bond represented by the formula R 0 —C(R 1 )═CHR 2 Formula (I) wherein —R 0 is chosen depending on the structure of a selected active agent (c) to be loaded into the microparticle and is chosen to have a structure that when combined with the other components of the microparticle provides a higher affinity of the selected active agent (c) for the microparticle; —each R 1 is chosen from hydrogen and substituted and unsubstituted, aliphatic, cycloaliphatic and aromatic hydrocarbon groups which groups optionally contain one or more moieties selected from the group of ester moieties, ether moieties, thioester moieties, thioether moieties, carbamate moieties, thiocarbamate moieties, amide moieties and other moieties comprising one or more heteroatoms, in particular one or more heteroatoms selected from S, O, P and N, each R 5 in particular independently being chosen from the group of hydrogen and substituted and unsubstituted alkyl groups, which alkyl groups optionally contain one or more heteroatoms, in particular one or more heteroatoms selected from P, S, O and N; —each R 2 is chosen from hydrogen, —COOCH 3 , —COOC 2 H 5 , —COOC 3 H 7 , and —COOC 4 H 9 .
• US8173350B2
  申请人：——

  公开号：US8173350B2

  公开（公告）日：2012-05-08
• [EN] MICROPARTICLE COMPRISING CROSS-LINKED POLYMER<br/>[FR] MICROPARTICULES COMPRENANT UN POLYMÈRE RÉTICULÉ
  申请人：DSM IP ASSETS BV

  公开号：WO2009040434A1

  公开（公告）日：2009-04-02

  Microparticle comprising a cross-linked polymer comprising (a) a cross-linker comprising two or mo re radically polymerizable groups, preferably selected from the group consisting of alkenes, sulfhydryl (SH), thioic, unsaturated esters, unsaturated urethanes, unsaturated ethers, and unsaturated amides; (b) a monofunctional reactive diluent comprising maximum one unsaturated C-C bond represented by the formula R0-C(R1)=CHR2 Formula (I) wherein -R0 is chosen depending on the structure of a selected active agent (c) to be loaded into the microparticle and is chosen to have a structure that when combined with the other components of the microparticle provides a higher affinity of the selected active agent (c) for the microparticle; -each R1 is chosen from hydrogen and substituted and unsubstituted, aliphatic, cycloaliphatic and aromatic hydrocarbon groups which groups optionally contain one or more moieties selected from the group of ester moieties, ether moieties, thioester moieties, thioether moieties, carbamate moieties, thiocarbamate moieties, amide moieties and other moieties comprising one or more heteroatoms, in particular one or more heteroatoms selected from S, O, P and N, each R5 in particular independently being chosen from the group of hydrogen and substituted and unsubstituted alkyl groups, which alkyl groups optionally contai n one or more heteroatoms, in particular one or more heteroatoms selected from P, S, O and N; -each R2 is chosen from hydrogen, -COOCH3, -COOC2H5, -COOC3H7, and -COOC4H9.