1-[[[3-[(2-Hydroxynaphthalen-1-yl)methylamino]naphthalen-2-yl]amino]methyl]naphthalen-2-ol | 1246182-68-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-[[[3-[(2-Hydroxynaphthalen-1-yl)methylamino]naphthalen-2-yl]amino]methyl]naphthalen-2-ol
• CAS: 1246182-68-2
• 化学式: C₃₂H₂₆N₂O₂
• 分子量: 470.571
• InChiKey: OZZGPVQNIJNMDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  64.5
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,1'-((naphthalene-2,3-diylbis(azanylylidene))bis(methanylylidene))bis(naphthalen-2-ol) 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 4.0h， 以78%的产率得到1-[[[3-[(2-Hydroxynaphthalen-1-yl)methylamino]naphthalen-2-yl]amino]methyl]naphthalen-2-ol
  参考文献：
  名称：

  Single sensor for multiple analytes: chromogenic detection of I− and fluorescent detection of Fe3+

  摘要：

  A novel receptor, designed with a combination of oxygen and nitrogen-binding sites for metal ions and hydrogen bond donor sites for anion binding, was synthesized. The receptor has been explored for the selective detection of I- against a range of physiologically relevant anions and cations through changes in its UV-vis spectra. On the other hand, receptor-binding selectivity for Fe3+ over a wide linear concentration range was observed through changes in the emission spectra. This is the first Letter of a sensor capable of detecting both I- and Fe3+ using two different detection modes. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.05.105