Ni(4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-oxy-1-naphtylidene)thiazole)2 | 354553-34-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Ni(4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-oxy-1-naphtylidene)thiazole)2
• CAS: 354553-34-7
• 化学式: C₅₀H₄₂N₄NiO₂S₂
• 分子量: 853.731
• InChiKey: XZGIAQUTIKOCHN-VSKOJFFASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ni(4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-oxy-1-naphtylidene)thiazole)2 以 neat (no solvent) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  A NEW CYCLOBUTANE-SUBSTITUTED SCHIFF BASE LIGAND AND ITS Co(II), Cu(II), Ni(II), AND Zn(II) COMPLEXES

  摘要：

  A new ligand, 4-(1-phenyl-1-methylcyclobutyl-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole (LH), has been synthesized starting from 1-phenyl-1-methyl-3-(2-chloro-1-oxoethyl) cyclobutane, thiourea and 2-hydroxy-1-napthalaldehyde. Mononuclear complexes with a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II), Ni(II) and Zn(II) salts. Structures of the ligand and its complexes are suggested based on elemental analyses, IR, C-13 and H-1 NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).

  DOI：

  10.1081/sim-100002045
• 作为产物：
  描述：

  4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole 、 nickel(II) acetate tetrahydrate 以 甲醇 为溶剂， 以84%的产率得到Ni(4-(1-phenyl-1-methylcyclobutane-3-yl)-2-(2-oxy-1-naphtylidene)thiazole)2
  参考文献：
  名称：

  A NEW CYCLOBUTANE-SUBSTITUTED SCHIFF BASE LIGAND AND ITS Co(II), Cu(II), Ni(II), AND Zn(II) COMPLEXES

  摘要：

  A new ligand, 4-(1-phenyl-1-methylcyclobutyl-3-yl)-2-(2-hydroxy-1-naphtylidene)thiazole (LH), has been synthesized starting from 1-phenyl-1-methyl-3-(2-chloro-1-oxoethyl) cyclobutane, thiourea and 2-hydroxy-1-napthalaldehyde. Mononuclear complexes with a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II), Ni(II) and Zn(II) salts. Structures of the ligand and its complexes are suggested based on elemental analyses, IR, C-13 and H-1 NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).

  DOI：

  10.1081/sim-100002045