N-ethyl-N-nitrosobutyrylamide | 99115-34-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-ethyl-N-nitrosobutyrylamide
• 英文别名: N-ethyl-N-nitroso-butyramide；N-Aethyl-N-nitroso-butyramid；N-ethyl-N-nitrosobutanamide
• CAS: 99115-34-1
• 化学式: C₆H₁₂N₂O₂
• 分子量: 144.173
• InChiKey: FICSEASAXAHNNK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  49.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-乙基丁酰胺 在 dinitrogen tetraoxide 、 二氧化氮 作用下， 以 氯仿 为溶剂， 以95%的产率得到N-ethyl-N-nitrosobutyrylamide
  参考文献：
  名称：

  Encapsulated Reagents for Nitrosation

  摘要：

  A novel class of stable, mild, and size-shape-selective nitrosating agents for secondary amides is introduced. These are based on reversible entrapment and release of reactive nitrosonium species by calix[4]arenes. The NO+ encapsulation controls the reaction selectivity.

  DOI：

  10.1021/ol0342195

文献信息

• Huisgen; Reimlinger, Justus Liebigs Annalen der Chemie, 1956, vol. 599, p. 161,178
  作者：Huisgen、Reimlinger

  DOI：——

  日期：——
• COMPOUNDS DERIVED FROM MUSCODOR FUNGI
  申请人：Jimenez Jorge I.

  公开号：US20120058058A1

  公开（公告）日：2012-03-08

  The present invention relates to novel compounds and compositions and the use of them for the control of fungal and bacterial pathogens, insect pests, acari, nematodes and other invertebrate pests including, but not limited to post-harvest and soil diseases, building mold remediation, and seed and grain sanitation.
• US8728442B2
  申请人：——

  公开号：US8728442B2

  公开（公告）日：2014-05-20
• [EN] COMPOUNDS DERIVED FROM MUSCODOR FUNGI<br/>[FR] COMPOSÉS DÉRIVÉS DE MUSCODOR FUNGI
  申请人：AGRAQUEST INC

  公开号：WO2010132509A2

  公开（公告）日：2010-11-18

  The present invention relates to novel compounds and compositions and the use of them for the control of fungal and bacterial pathogens, insect pests, acari, nematodes and other invertebrate pests including, but not limited to post-harvest and soil diseases, building mold remediation, and seed and grain sanitation.
• Encapsulated Reagents for Nitrosation
  作者：Grigory V. Zyryanov、Dmitry M. Rudkevich

  DOI：10.1021/ol0342195

  日期：2003.4.1

  A novel class of stable, mild, and size-shape-selective nitrosating agents for secondary amides is introduced. These are based on reversible entrapment and release of reactive nitrosonium species by calix[4]arenes. The NO+ encapsulation controls the reaction selectivity.