(1-methyl-2,3-diphenylphosphirene)pentacarbonyltungsten | 82265-70-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (1-methyl-2,3-diphenylphosphirene)pentacarbonyltungsten
• 英文别名: Carbon monoxide;1-methyl-2,3-diphenylphosphirene;tungsten
• CAS: 82265-70-1
• 化学式: C₂₀H₁₃O₅PW
• 分子量: 548.144
• InChiKey: ZHOUWOYDSDDCLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (1-methyl-2,3-diphenylphosphirene)pentacarbonyltungsten 、 苯乙炔 、 四(三苯基膦)钯 以45%的产率得到
  参考文献：
  名称：

  MARINETTI, ANGELA;MATHEY, FRANCOIS, TETRAHEDRON LETT., 28,(1987) N 42, 5021-5024

  摘要：

  DOI：
• 作为产物：
  描述：

  (2,3-diphenylphosphirene)pentacarbonyltungsten 在 sodium hydroxide 、 四丁基硫酸氢铵 、 碘甲烷 作用下， 以 二氯甲烷 、 水 为溶剂， 以45%的产率得到(1-methyl-2,3-diphenylphosphirene)pentacarbonyltungsten
  参考文献：
  名称：

  Deschamps, Bernard; Mathey, Francois, New Journal of Chemistry, 1988, vol. 12, p. 755 - 760

  摘要：

  DOI：

文献信息

• Generation and Reactivity of Methylphosphaketene in the Coordination Sphere of Tungsten
  作者：Yanli Mao、Zhiyue Wang、Rakesh Ganguly、François Mathey

  DOI：10.1021/om300333v

  日期：2012.7.9

  pentacarbonyltungsten complex and dimethyl acetylenedicarboxylate can be used as a precursor for the methylphosphaketene tungsten complex under UV irradiation at room temperature. Under these conditions, the phosphaketene complex easily loses CO to give the methylphosphinidene complex. Highly reactive alcohols and primary alkylamines trap both the phosphaketene and the phosphinidene complexes. Less reactive

  1-甲基-2-酮-1,2-二氢膦亚甲基五羰基钨配合物和乙酰二羧酸二甲酯之间的[4 + 2]环加合物可以用作室温下紫外线照射下甲基磷烯钨配合物的前体。在这些条件下，磷烯配合物容易失去CO而得到甲基次亚膦配合物。高反应性的醇和伯烷基胺会同时捕获磷烯和次膦烯的配合物。反应性较低的苯酚和笨重的胺类与炔烃和共轭二烯一起只能捕获次膦化合物。
• 3<i>H</i>-Benzophosphepine Complexes:  Versatile Phosphinidene Precursors
  作者：Mark L. G. Borst、Rosa E. Bulo、Danièle J. Gibney、Yonathan Alem、Frans J. J. de Kanter、Andreas W. Ehlers、Marius Schakel、Martin Lutz、Anthony L. Spek、Koop Lammertsma

  DOI：10.1021/ja054885w

  日期：2005.12.1

  The synthesis of a variety of benzophosphepine complexes [R = Ph, t-Bu, Me; MLn = W(CO)(5), Mo(CO)(5), Cr(CO)(5), Mn(CO)(2)Cp] by two successive hydrophosphinations of 1,2-diethynylbenzene is discussed in detail. The first hydrophosphination step proceeds at ambient temperature without additional promoters, and subsequent addition of base allows full conversion to benzophosphepines. Novel benzeno-1,4-diphosphinanes were isolated as side products. The benzophosphepine complexes themselves serve as convenient phosphinidene precursors at elevated, substituent-dependent temperatures (> 55 degrees C). Kinetic and computational analyses support the proposal that the phosphepine-phosphanorcaradiene isomerization is the rate-determining step. In the absence of substrate, addition of the transient phosphinidene to another benzophosphepine molecule is observed, and addition to 1,2-diethynylbenzene furnishes a delicate bidentate diphosphirene complex.
• Generation and trapping of terminal phosphinidene complexes. Synthesis and x-ray crystal structure of stable phosphirene complexes
  作者：Angela Marinetti、Francois Mathey、Jean Fischer、Andre Mitschler

  DOI：10.1021/ja00380a029

  日期：1982.8