{vanadyl(IV)(OH)(saccharin)(saccharinate)(water)2} | 148822-26-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: {vanadyl(IV)(OH)(saccharin)(saccharinate)(water)2}
• CAS: 148822-26-8
• 化学式: C₁₄H₁₄N₂O₁₀S₂V
• 分子量: 485.346
• InChiKey: NWGAYQQITIIPPS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硫酸氧钒(Ⅳ)水合物 、 saccharin sodium salt 以 水 为溶剂， 以0%的产率得到{vanadyl(IV)(OH)(saccharin)(saccharinate)(water)2}
  参考文献：
  名称：

  Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat

  摘要：

  The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.

  DOI：

  10.1007/bf00814132