| 286431-03-6

• CAS: 286431-03-6
• 化学式: C₂₄H₂₀B*C₃₆H₅₃BN₇P₂Ru
• 分子量: 1076.93
• InChiKey: KZSHDSXDZBXSGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 K(OC(CH₃)3) 作用下， 以 四氢呋喃 为溶剂， 以66%的产率得到[(hydrotris(pyrazolyl)borate)Ru(σ-η1-C6H4C(C6H5)=NH)(1,2-bis(diisopropylphosphino)ethane)2]
  参考文献：
  名称：

  Synthesis and properties of hydrotris(pyrazolyl)borate (Tp) ruthenium complexes with benzophenone imine: X-ray crystal structure of [TpRu(HN=CPh2)(PEt3)2][BPh4]

  摘要：

  The complexes [TpRuCl(dippe)] (dippe = 1,2-bis(diisopropylphosphino)ethane) and [TpRuCl(PEt3)(2)] react with HN=CPh2 and NaBPh4 in MeOH affording the cationic mononuclear imine derivatives [TpRu(HN=CPh2)(dippe)][BPh4] and [TpRu(HN=CPh2)(PEt3)(2)][BPh4], respectively. The X-ray crystal structure of the latter has been determined. The reaction of [TpRuCl(PMePr2)((MeCN)-C-i)] with HN=CPh2 led to the neutral imine derivative [TpRuCl((PMePr2)-Pr-i)(HN=CPh2)], which adds a second imine ligand upon chloride dissociation affording the cationic bis(imine) complex [TpRu((PMePr2)-Pr-i)(HN=CPh2)(2)](+). The cationic complexes [TpRu(HN=CPh2)(dippe)][BPh4] and [TpRu(HN=CPh2)(PE3)(2)][BPh4] react with KOBut in tetrahydrofuran yielding the neutral metalated species [TpRu(sigma-eta(1)-C6H4C(Ph)=NH)(dippe)] and the phenyl complex [TpRu(sigma-eta(1)-C6H5)(PEt3)(2)], respectively. All compounds were characterized by IR, NMR and microanalysis. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00002-5
• 作为产物：
  描述：

  二苯甲酮亚胺 、 [(hydrotris(pyrazolyl)borate)RuCl(1,2-bis(diisopropylphosphino)ethane)] 、 四苯硼钠 以 甲醇 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Synthesis and properties of hydrotris(pyrazolyl)borate (Tp) ruthenium complexes with benzophenone imine: X-ray crystal structure of [TpRu(HN=CPh2)(PEt3)2][BPh4]

  摘要：

  The complexes [TpRuCl(dippe)] (dippe = 1,2-bis(diisopropylphosphino)ethane) and [TpRuCl(PEt3)(2)] react with HN=CPh2 and NaBPh4 in MeOH affording the cationic mononuclear imine derivatives [TpRu(HN=CPh2)(dippe)][BPh4] and [TpRu(HN=CPh2)(PEt3)(2)][BPh4], respectively. The X-ray crystal structure of the latter has been determined. The reaction of [TpRuCl(PMePr2)((MeCN)-C-i)] with HN=CPh2 led to the neutral imine derivative [TpRuCl((PMePr2)-Pr-i)(HN=CPh2)], which adds a second imine ligand upon chloride dissociation affording the cationic bis(imine) complex [TpRu((PMePr2)-Pr-i)(HN=CPh2)(2)](+). The cationic complexes [TpRu(HN=CPh2)(dippe)][BPh4] and [TpRu(HN=CPh2)(PE3)(2)][BPh4] react with KOBut in tetrahydrofuran yielding the neutral metalated species [TpRu(sigma-eta(1)-C6H4C(Ph)=NH)(dippe)] and the phenyl complex [TpRu(sigma-eta(1)-C6H5)(PEt3)(2)], respectively. All compounds were characterized by IR, NMR and microanalysis. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00002-5