3-[(2-hydroxyphenyl)iminomethyl]-1H-benzo[h]quinolin-2-one | 1360468-55-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 3-[(2-hydroxyphenyl)iminomethyl]-1H-benzo[h]quinolin-2-one
• CAS: 1360468-55-8
• 化学式: C₂₀H₁₄N₂O₂
• 分子量: 314.343
• InChiKey: JSUOWTVVMFPVOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-[(2-hydroxyphenyl)iminomethyl]-1H-benzo[h]quinolin-2-one 、 bis-triphenylphosphine-palladium(II) chloride 在 triethyl amine 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Novel binuclear palladium(II) complexes of 2-oxoquinoline-3-carbaldehyde Schiff bases: Synthesis, structure and catalytic applications

  摘要：

  A series of novel binuclear Pd(II) complexes of the type [(PPh3)(2)ClPd(L)PdCI] [where L = dianionic bridged ligands derived from 2-oxo-1,2-dihydroquinoline-3-carbaldehyde or its derivatives with o-aminophenol/o-aminothiophenol] have been reported. The new complexes have been characterized by elemental analysis, FT-IR, UV-Vis and NMR (H-1 and P-31) spectroscopic techniques. The coordination mode of the ligands and the geometry of the complexes were confirmed by single crystal X-ray crystallography of one of the complexes. The catalytic efficiency of one of the binuclear Pd(II) complexes was tested for N-arylation of imidazole. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.12.017
• 作为产物：
  描述：

  2-氨基苯酚 、 2-oxo-1,2-dihydro-benzo[h]quinoline-3-carbaldehyde 以 甲醇 为溶剂， 反应 6.0h， 生成 3-[(2-hydroxyphenyl)iminomethyl]-1H-benzo[h]quinolin-2-one
  参考文献：
  名称：

  Novel binuclear palladium(II) complexes of 2-oxoquinoline-3-carbaldehyde Schiff bases: Synthesis, structure and catalytic applications

  摘要：

  A series of novel binuclear Pd(II) complexes of the type [(PPh3)(2)ClPd(L)PdCI] [where L = dianionic bridged ligands derived from 2-oxo-1,2-dihydroquinoline-3-carbaldehyde or its derivatives with o-aminophenol/o-aminothiophenol] have been reported. The new complexes have been characterized by elemental analysis, FT-IR, UV-Vis and NMR (H-1 and P-31) spectroscopic techniques. The coordination mode of the ligands and the geometry of the complexes were confirmed by single crystal X-ray crystallography of one of the complexes. The catalytic efficiency of one of the binuclear Pd(II) complexes was tested for N-arylation of imidazole. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.12.017