dimethyl[4-(naphthalen-1-yl)butyl]phenylsilane | 1224868-05-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: dimethyl[4-(naphthalen-1-yl)butyl]phenylsilane
• 英文别名: Dimethyl-(4-naphthalen-1-ylbutyl)-phenylsilane；dimethyl-(4-naphthalen-1-ylbutyl)-phenylsilane
• CAS: 1224868-05-6
• 化学式: C₂₂H₂₆Si
• 分子量: 318.534
• InChiKey: NGBWJKDCOSSSDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.78
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-(but-3-en-1-yl)naphthalene 、 二甲基苯基硅烷 在 {Rh₂(1,5-cyclooctadiene)2[2,6-(Ph₂PCH₂)2C₆H₃O]}(ClO₄) 作用下， 反应 72.0h， 以43%的产率得到dimethyl[4-(naphthalen-1-yl)butyl]phenylsilane
  参考文献：
  名称：

  Synthesis of Oxygen- and Sulfur-Bridged Dirhodium Complexes and Their Use As Catalysts in the Chemoselective Hydrogenation of Alkenes

  摘要：

  Oxygen-bridged and sulfur-bridged rhodium homobimetallic complexes were synthesized as airstable crystals by using 2,6-bis(phosphanylmethyl)phenolate and -thiophenolate as the ligands, respectively. The oxygen-bridged dirhodium complex has a symmetrical structure where the carbon atom at the ipso position, oxygen, and two rhodium atoms are located in the same plane. It is thermally stable compared to the sulfur-bridged dirhodium complex and shows catalytic activity for hydrogenation of alkenes with high chemoselectivity.

  DOI：

  10.1021/om100067r

文献信息

• Synthesis of Oxygen- and Sulfur-Bridged Dirhodium Complexes and Their Use As Catalysts in the Chemoselective Hydrogenation of Alkenes
  作者：Chuan Zhu、Noriaki Yukimura、Motoki Yamane

  DOI：10.1021/om100067r

  日期：2010.5.10

  Oxygen-bridged and sulfur-bridged rhodium homobimetallic complexes were synthesized as airstable crystals by using 2,6-bis(phosphanylmethyl)phenolate and -thiophenolate as the ligands, respectively. The oxygen-bridged dirhodium complex has a symmetrical structure where the carbon atom at the ipso position, oxygen, and two rhodium atoms are located in the same plane. It is thermally stable compared to the sulfur-bridged dirhodium complex and shows catalytic activity for hydrogenation of alkenes with high chemoselectivity.