Rhodamine 3B cation | 14899-09-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: Rhodamine 3B cation
• 英文别名: rhodamine 3B；3,6-bis-diethylamino-9-(2-ethoxycarbonyl-phenyl)-xanthenylium；Rhodamin 3B；Xanthylium, 3,6-bis(diethylamino)-9-(2-(ethoxycarbonyl)phenyl)-；[6-(diethylamino)-9-(2-ethoxycarbonylphenyl)xanthen-3-ylidene]-diethylazanium
• CAS: 14899-09-3
• 化学式: C₃₀H₃₅N₂O₃
• 分子量: 471.619
• InChiKey: CJHZYMDXCQLLFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  35
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  41.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Rhodamine 3B cation 在 肼 作用下， 以 乙醇 为溶剂， 生成 若丹明B酰肼
  参考文献：
  名称：

  NIR- and FRET-Based Sensing of Cu²⁺ and S^2- in Physiological Conditions and in Live Cells

  摘要：

  We have synthesized a new indole functionalized rhodamine derivative L-1 which specifically binds to Cu2+ in the presence of large excess of other competing ions with visually observable changes in their electronic and fluorescence spectral behavior. These spectral changes are significant enough in the NIR and visible region of the spectrum and thus enable naked eye detection. The receptor, L-1, could be employed as a resonance energy transfer (RET) based sensor for detection of Cu2+ based on the process involving the donor indole and the acceptor Cu2+ bound xanthene fragment. Studies reveal that L-1-Cu complex is selectively and fully reversible in presence of sulfide anions. Further, fluorescence microscopic studies confirmed that the reagent L-1 could also be used as an imaging probe for detection of uptake of these ions in HeLa cells.

  DOI：

  10.1021/ic301872q

文献信息

• HYBRID BLOCK COPOLYMER MICELLES WITH MIXED STEREOCHEMISTRY FOR ENCAPSULATION OF HYDROPHOBIC AGENTS
  申请人：SILL Kevin N.

  公开号：US20080274173A1

  公开（公告）日：2008-11-06

  The present invention relates to the field of polymer chemistry and more particularly to multiblock copolymers and micelles comprising the same.

  本发明涉及聚合物化学领域，更具体地说是涉及多嵌段共聚物以及包含该共聚物的胶束。
• XANTHENE-BASED PURPLE DYE COMPOUND, COLORING RESIN COMPOSITION FOR COLOR FILTER CONTAINING SAME AND COLOR FILTER USING SAME
  申请人：KYUNG-IN SYNTHETIC CO., LTD.

  公开号：US20150322265A1

  公开（公告）日：2015-11-12

  The present disclosure relates to a purple dye compound for a color filter and a coloring resin composition for a color filter containing the same. The novel xanthene-based purple dye compound or the polymer dye compound obtained using the same as a monomer has superior solvent resistance and superior miscibility with a pigment in an organic solvent. Further, it exhibits superior heat resistance, chemical resistance, light resistance and brightness due to the homopolymer structure. Accordingly, a coloring resin composition containing the same can be used widely as a dye for synthetic resins and synthetic fibers, as a coloring agent for polymer materials, for a color filter used in LCDs, PDPs, etc., and so forth.

  本公开涉及一种用于彩色滤光片的紫色染料化合物以及包含该化合物的彩色滤光片着色树脂组合物。这种基于新型偶氮染料的紫色染料化合物或者使用其作为单体获得的聚合物染料化合物具有优越的溶剂抗性和在有机溶剂中与颜料的优越混溶性。此外，由于其均聚物结构，它表现出优越的耐热性、耐化学性、耐光性和亮度。因此，包含该化合物的着色树脂组合物可以广泛用作合成树脂和合成纤维的染料，用作聚合物材料的着色剂，用于液晶显示器、等离子显示器等中使用的彩色滤光片等。
• Luminous Change of Rhodamine 3B Incorporated into Titanate Nanosheet/Decyltrimethylammonium Hybrids under Humid Atmosphere
  作者：Ryo Sasai、Nobuo Iyi、Hiroki Kusumoto

  DOI：10.1246/bcsj.20100343

  日期：2011.5.15

  In this paper, the structural and spectroscopic properties of rhodamine 3B (R3B) cations incorporated into titanate nanosheet (TNS)/decyltrimethylammonium (C10TMA) cation hybrid was investigated in the presence and absence of adsorbed water. Powder X-ray diffraction measurement under various relative humidity indicated that the TNS/C10TMA/R3B hybrid had at least two water-adsorption sites with different affinity for water in the 2D nanospace of TNS stacked structure. Intensity reduction and blue shift in diffuse reflectance and photoluminescence spectra of the TNS/C10TMA/R3B hybrid powder was observed by water adsorption. This spectroscopic behavior could be explained as lowering of electrostatic interaction between the cation group of R3B and cation exchange sites on the TNS surface.

  本文研究了在存在和不存在吸附水的情况下，掺入钛酸纳米片（TNS）/癸基三甲基铵（C10TMA）阳离子杂化物的罗丹明3B（R3B）阳离子的结构和光谱特性。在各种相对湿度下进行的粉末X射线衍射测量表明，在TNS堆叠结构的二维纳米空间中，TNS/C10TMA/R3B杂化物至少有两个对水具有不同亲和力的水吸附位点。通过水吸附，观察到TNS/C10TMA/R3B杂化粉末的漫反射和光致发光光谱的强度降低和蓝移。这种光谱行为可以解释为R3B阳离子基团与TNS表面上的阳离子交换位点之间的静电相互作用降低。
• Heterobifunctional poly(ethyleneglycol) containing acid-labile amino protecting groups and uses thereof
  申请人：Breitenkamp Kurt

  公开号：US20080188638A1

  公开（公告）日：2008-08-07

  The present invention provides bifunctional polymers, methods of preparing the same, and intermediates thereto. These compounds are useful in a variety of applications including the PEGylation of biologically active molecules. The invention also provides methods of using said compounds and compositions thereof.

  本发明提供了双功能聚合物，其制备方法以及中间体。这些化合物在各种应用中都有用，包括对生物活性分子进行聚乙二醇化。本发明还提供了使用这些化合物和其组成物的方法。
• MODIFIER FOR EXPANDABLE AND EXPANDED POLYSTYRENE MATERIALS AND EXPANDABLE AND EXPANDED POLYSTYRENE MATERIALS SO MODIFIED
  申请人：Termo Organika SP. Z O.O.

  公开号：EP2694596A1

  公开（公告）日：2014-02-12