chloro[2,2',2''-nitrilotris[ethanolato]-N,O,O',O'']cobalt | 36217-04-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: chloro[2,2',2''-nitrilotris[ethanolato]-N,O,O',O'']cobalt
• CAS: 36217-04-6；131501-20-7；116737-73-6；59307-43-6
• 化学式: C₆H₁₄NO₃*Cl*Co
• 分子量: 242.628
• InChiKey: GIVKNPPCLDVDRS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  sodium hydroxide 、 chloro[2,2',2''-nitrilotris[ethanolato]-N,O,O',O'']cobalt 以 sodium hydroxide 为溶剂， 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.B1, 73, page 155 - 158

  摘要：

  DOI：
• 作为产物：
  描述：

  三乙醇胺 、 cobalt(II) chloride 以 乙醇 为溶剂， 以75%的产率得到chloro[2,2',2''-nitrilotris[ethanolato]-N,O,O',O'']cobalt
  参考文献：
  名称：

  El-Essawi, Mohyi M.; Masoud, Mamdouh S.; Amr, Amira M., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990, vol. 20, p. 839 - 850

  摘要：

  DOI：

文献信息

• 433. Ammines. Part X. Cobaltous and cupric compounds from tris-(β-hydroxyethyl)amine. New method of formation of ammino-cupric salts
  作者：J. C. Duff、E. H. Steer

  DOI：10.1039/jr9320002861

  日期：——
• Synthesis and structural characterization of 1-(3-aminopropyl)silatrane and some new derivatives
  作者：Ana–Maria-Corina Dumitriu、Maria Cazacu、Sergiu Shova、Constantin Turta、Bogdan C. Simionescu

  DOI：10.1016/j.poly.2011.11.014

  日期：2012.2

  The research goal was to synthesize and structurally characterize a silatrane intended to be subsequently incorporated into metal complex structures. 3-Aminopropyltrialkoxysilane was reacted with triethanolamine in 1:1 molar ratio, either in bulk, in the presence of metallic sodium, or in a solvent mixture. 1-(3-Aminopropyl)silatrane in carbamate form or having free amine groups was obtained. The latter was reacted with 2-hydroxybenzaldehyde, 2,4-dihydroxybenzaldehyde and CoCl2 or with CoCl2 only. The crystalline reaction products were characterized by elemental and spectral (FTIR and H-1 NMR) analyses and single crystal X-ray diffractometry, which revealed the formation of new, either sought (1-(3-aminopropyl)silatrane, 1-(3-salicyliminopropyl)silatrane) or unexpected (N-carboxylated 1-(3-aminopropyl)silatrane and 1-chlorocobaltrane) structures. (C) 2011 Elsevier Ltd. All rights reserved.
• Radha, Akella; Seshasayee, M.; Kumar, V., Acta Crystallographica, Section C: Crystal Structure Communications, <hi>1989</hi>, vol. 45, p. 882 - 884
  作者：Radha, Akella、Seshasayee, M.、Kumar, V.、Aravamudan, G.

  DOI：——

  日期：——