[Ag(2-amino-3-methylpyridine)2(2-hydroxy-3-methoxybenzoate)] | 1268374-85-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: [Ag(2-amino-3-methylpyridine)2(2-hydroxy-3-methoxybenzoate)]
• 英文别名: [Ag(3MP)2(HMB)]
• CAS: 1268374-85-1
• 化学式: C₂₀H₂₃AgN₄O₄
• 分子量: 491.295
• InChiKey: LVUIZWTUQCTVID-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-氨基-3-甲基吡啶 、 3-甲氧基水杨酸 、 silver(l) oxide 以 氨 为溶剂， 以62%的产率得到[Ag(2-amino-3-methylpyridine)2(2-hydroxy-3-methoxybenzoate)]
  参考文献：
  名称：

  Syntheses and structural characterization of silver(I) complexes with pyridine and carboxylate derivatives

  摘要：

  Self-assembly between silver carboxylates with 2-aminopyridine derivatives give two silver(I) complexes, [[Ag(5MP)(2)(CNB)] center dot NH3 (I) and [Ag(3MP)(2)(HMB)] (II), where 5MP, CNB, 3MP, and HMB represent 2-amin-5-methylpyridine, 5-chloro-2-nitrobenzoate, 2-amino-3-methylpyridine, and 2-hydroxy-3-methoxybenzoate, respectively. The crystal structures of the complexes were investigated. The Ag atom in each complex is coordinated by two pyridine N atoms and weakly coordinated by a carboxylic O atom. The crystal of I is triclinic: space group P (1) over bar a = 7.562(2), b = 11.708(3), c = 12.933(3) angstrom, alpha = 103.378(4)degrees, beta = 93.910(4)degrees, gamma = 99.001(4)degrees, V = 1093.7(5) angstrom(3), Z = 2. The crystal of II is monoclinic: space group C2/c, a = 25.727(5), b = 10.274(2), c = 19.872(4) angstrom, beta = 126.62(3)degrees, V = 4215.7(15) angstrom(3), Z = 4. DOI: 10.1134/ S107032841101009X

  DOI：

  10.1134/s107032841101009x