salicylaldehyde-N,N-di(iso-propyl) semicarbazone | 637748-81-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: salicylaldehyde-N,N-di(iso-propyl) semicarbazone
• CAS: 637748-81-3
• 化学式: C₁₄H₂₁N₃O₂
• 分子量: 263.34
• InChiKey: LUTBOCVMXQROPT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 salicylaldehyde-N,N-di(iso-propyl) semicarbazone 以 甲醇 、 二氯甲烷 为溶剂， 以65%的产率得到[bis(salicylaldehyde-N,N-di(iso-propyl) semicarbazone)dichlorodicopper(II)] tetrahydrate
  参考文献：
  名称：

  Synthesis, characterization and physicochemical properties of copper(II) complexes containing salicylaldehyde semicarbazone

  摘要：

  Copper(II) complexes containing a series of salicylaldehyde semicarbazone ligands have been prepared and characterized by a range of physicochemical techniques. The X-ray structure of [Cu(HBnZ(2))Cl] . H2O (5) (where HBnz(2) is salicylaldehyde-N,N-dibenzyl semicarbazone) shows the complex is monomeric and the copper atom is four coordinated in a distorted square planar geometry. The ligand chelates the copper in a tridentate fashion through the imine N, carbonyl O and phenolato O with the fourth position being occupied by coordinated Cl. The compound [Cu(Ph-2) . H2O] (4) (where Ph-2 is salicylaldehyde-N,N-diphenyl semicarbazone) is also formulated as a monomer whereas all other complexes are assumed to have a side-by-side dimeric arrangement of the metal chelating with the phenolate bridging the Cu(II) centres. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00402-9