Thionyl tetrafluoride gas reacts efficiently with primary amines to form reactive iminosulfur oxydifluoride compounds. These dual SVI—F loaded iminosulfur oxydifluoride compounds, in turn, readily react with secondary amines or aryloxy silyl ethers (ArO—SiR3), yielding the corresponding fused heteroatom-linked substrates. Iminosulfur oxyfluoride polymers also are provided by disclosed methods.
四氟化硫酰气体能有效地与
伯胺反应,生成活性
亚胺硫二氟化氧化合物。这些双 SVI-F 负载的二
氟化
亚胺硫化合物又很容易与仲胺或芳氧基
硅醚(ArO-SiR3)反应,生成相应的融合杂原子连接基质。此外,还可通过公开的方法制备
硫氧
氟化
亚胺聚合物。