N,N'-bis(1,2,3,4-tetrahydro-5-naphthalenamino)glyoxime | 1040185-49-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: N,N'-bis(1,2,3,4-tetrahydro-5-naphthalenamino)glyoxime
• 英文别名: 1-N,2-N-dihydroxy-1-N',2-N'-bis(5,6,7,8-tetrahydronaphthalen-1-yl)ethanediimidamide
• CAS: 1040185-49-6
• 化学式: C₂₂H₂₆N₄O₂
• 分子量: 378.474
• InChiKey: AEXYRJGJWUTVRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  89.2
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  nickel(II) chloride hexahydrate 、 N,N'-bis(1,2,3,4-tetrahydro-5-naphthalenamino)glyoxime 以 乙醇 为溶剂， 以48%的产率得到tris[N,N'-bis(1,2,3,4-tetrahydro-5-naphthalenamino)glyoximato]nickel(II) dichloride
  参考文献：
  名称：

  New insight in coordination of vic-dioximes: Bis- and tris(E,E-dioximato)Ni(II) complexes

  摘要：

  N, N'-Bis[allylamino] glyoxime, N,N'-bis[anilino] glyoxime, and N, N'-bis[1,2,3,4- tetrahydro-5-naphthalenamino] glyoxime have been prepared from corresponding amines and (E, E)-dichloroglyoxime. These ligands gave orange-red compound with NiCl(2) in less acidic medium (pH similar to 5) that are bis(E, E-dioximato) nickel(II) complexes {[(E, E)-Ni(HL)(2)]} (1a-3a) and green compounds in acidic medium (pH similar to 2) that are tris(E, E-dioximato) nickel(II) dichloride complexes {[(E, E)- Ni(LH(2))(3)]Cl(2)} (1b-3b). The crystal structures of all complexes have been determined by X-ray diffraction on a single crystal. The study of absorption spectra of these two types of complexes shows that they may be converted to each other by addition of acids (1a-3a) or bases (1b-3b) and there is no way for the amphi form. (C) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.11.019