1-[2-[3',6'-Bis(ethylamino)-2',7'-dimethyl-3-oxospiro[isoindole-1,9'-xanthene]-2-yl]ethyl]-3-(3-triethoxysilylpropyl)urea | 1309827-62-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 1-[2-[3',6'-Bis(ethylamino)-2',7'-dimethyl-3-oxospiro[isoindole-1,9'-xanthene]-2-yl]ethyl]-3-(3-triethoxysilylpropyl)urea
• CAS: 1309827-62-0
• 化学式: C₃₈H₅₃N₅O₆Si
• 分子量: 703.954
• InChiKey: FKOAUWJUAHLSMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.76
• 重原子数：
  50
• 可旋转键数：
  17
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  122
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  异氰酸丙基三乙氧基硅烷 、 N-(rhodamine-6G)lactam-ethylenediamine 以 甲苯 为溶剂， 反应 5.0h， 以69%的产率得到1-[2-[3',6'-Bis(ethylamino)-2',7'-dimethyl-3-oxospiro[isoindole-1,9'-xanthene]-2-yl]ethyl]-3-(3-triethoxysilylpropyl)urea
  参考文献：
  名称：

  Functionalized magnetic core–shell Fe3O4@SiO2 nanoparticles as selectivity-enhanced chemosensor for Hg(II)

  摘要：

  A colorimetric and "turn-on" fluorescent chemosensor Rho-Fe3O4@SiO2 for Hg2+ in which N-(rhodamine-6G)lactam-ethylenediamine (Rho-en) is conjugated with the magnetic core shell Fe3O4@SiO2 NPs has been strategically designed and synthesized. The final product was characterized by X-ray power diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectra (FTIR) and UV-visible absorption and fluorescence emission. Fluorescence and UV-visible spectra results showed that the resultant multifunctional nanoparticles Rho-Fe3O4@SiO2 exhibited selective 'turn-on' type fluorescent enhancements and distinct color changes with Hg2+. The selectivity of the Rho-Fe3O4@SiO2 for Hg(II) ion is better than that of the Rho-en in the same conditions. In addition, the presence of magnetic Fe3O4 nanoparticles in the sensor Rho-Fe3O4@SiO2 NPs would also facilitate the magnetic separation of the Hg(11) Rho-Fe3O4@SiO2 from the solution. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.01.012