2,2'-((butane-1,4-diylbis(azaneylylidene))bis(methaneylylidene))bis(4-nitrophenol) | 1204603-99-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,2'-((butane-1,4-diylbis(azaneylylidene))bis(methaneylylidene))bis(4-nitrophenol)
• CAS: 1204603-99-5
• 化学式: C₁₈H₁₈N₄O₆
• 分子量: 386.364
• InChiKey: QOXJUPDEDOMQAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.23
• 重原子数：
  28.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  151.46
• 氢给体数：
  2.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  5-硝基水杨醛 、 四亚甲基二胺 以 甲醇 为溶剂， 以88.5%的产率得到2,2'-((butane-1,4-diylbis(azaneylylidene))bis(methaneylylidene))bis(4-nitrophenol)
  参考文献：
  名称：

  Synthesis and characterization of nitro-Schiff bases derived from 5-nitro-salicylaldehyde and various diamines and their complexes of Co(II)

  摘要：

  Some neutral tetradentate N2O2 type complexes of Co(II) have been synthesized using Schiff bases formed by condensation of 5-nitro-salicylaldehyde with various diamines in alcohol. The nature of the ligands and complexes was established by spectroscopic techniques. The Schiff bases are bivalent anions with tetradentate ONNO donors derived from phenolic oxygen and azomethine nitrogen. IR and UV-Vis spectral data suggest that all the complexes are square-planar.

  DOI：

  10.1080/00958970903225866