[PtMe2(2-(Me2NCH2CH2NCH)C10H7)] | 420134-57-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [PtMe2(2-(Me2NCH2CH2NCH)C10H7)]
• CAS: 420134-57-2
• 化学式: C₁₇H₂₄N₂Pt
• 分子量: 451.471
• InChiKey: DYRFIDHUMYAFDX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [PtMe2(2-(Me2NCH2CH2NCH)C10H7)] 以 甲苯 为溶剂， 以83%的产率得到[PtMe2(2-(Me2NCH2CH2NCH)C10H6)]
  参考文献：
  名称：

  Regioselective activation of CH bonds of naphthyl imines at platinum(II). Crystal structures of [PtMe{1-(2′-ClC6H4CH2NCH)C10H6}PPh3] and [PtMe{2-(2′-ClC6H4CH2NCH)C10H6}PPh3]

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(Me2NCH2CH2NCH)C10H7 (2a) and 2-(Me2NCH2CH2NCH)C10H7 (2b) carried out in acetone at room temperature produced compounds [PtMe2 {1-(Me2NCH2CH2NCH)C10H7}] (3a) and [PtMe2{1- (Me2NCH2CH2NCH)C10H7}] (3b), respectively, in which the imines act as bidentate [N,N] ligands. cyclometallated [C,N,N'] compounds [PtMe{1-(Me2NCH2CH2NCH)C10H6}] (4a) and [PtMe{2-(Me2NCH2CH2NCH)C10H6}] (4b) were obtained by refluxing toluene solutions of compounds 3a or 3b. Reaction Of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(2'-ClC6H4CH2NCH)C10H7 (2c) and 2-(2'-ClC6H4CH2NCH)C10H7 (2d) produced straightforward metallation to yield [PtMe{1-(2'-ClC6H2CH2NCH)C10H6}SMe2] (5c) and [PtMe{2-(2'-ClC6H4CH2NCH)C10H6}SMe2] (5d) containing a [CN] ligand. Triphenylphosphine derivatives [PtMe{1-(2'-ClC6H4CH2NCH)C10H6} PPh3] (6c) and [PtMe{2-(2'-ClC6H4CH2NCH)C(10)H6}PPh3] (6d) were also prepared. All compounds were characterised by NMR spectroscopics and 6e and 6d were also characterised crystallographically. For both [CN,N'] and [CN] systems, the metallation took place regioselectively at beta-positions of the naphthyl group, (C) 2002 Elsevier Science BN. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01230-x
• 作为产物：
  描述：

  bis[dimethyl(μ-dimethylsulfide)platinum(II)] 、 2-(Me2NCH2CH2NCH)C10H7 以 丙酮 为溶剂， 以76%的产率得到[PtMe2(2-(Me2NCH2CH2NCH)C10H7)]
  参考文献：
  名称：

  Regioselective activation of CH bonds of naphthyl imines at platinum(II). Crystal structures of [PtMe{1-(2′-ClC6H4CH2NCH)C10H6}PPh3] and [PtMe{2-(2′-ClC6H4CH2NCH)C10H6}PPh3]

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(Me2NCH2CH2NCH)C10H7 (2a) and 2-(Me2NCH2CH2NCH)C10H7 (2b) carried out in acetone at room temperature produced compounds [PtMe2 {1-(Me2NCH2CH2NCH)C10H7}] (3a) and [PtMe2{1- (Me2NCH2CH2NCH)C10H7}] (3b), respectively, in which the imines act as bidentate [N,N] ligands. cyclometallated [C,N,N'] compounds [PtMe{1-(Me2NCH2CH2NCH)C10H6}] (4a) and [PtMe{2-(Me2NCH2CH2NCH)C10H6}] (4b) were obtained by refluxing toluene solutions of compounds 3a or 3b. Reaction Of [Pt2Me4(mu-SMe2)(2)] with ligands 1-(2'-ClC6H4CH2NCH)C10H7 (2c) and 2-(2'-ClC6H4CH2NCH)C10H7 (2d) produced straightforward metallation to yield [PtMe{1-(2'-ClC6H2CH2NCH)C10H6}SMe2] (5c) and [PtMe{2-(2'-ClC6H4CH2NCH)C10H6}SMe2] (5d) containing a [CN] ligand. Triphenylphosphine derivatives [PtMe{1-(2'-ClC6H4CH2NCH)C10H6} PPh3] (6c) and [PtMe{2-(2'-ClC6H4CH2NCH)C(10)H6}PPh3] (6d) were also prepared. All compounds were characterised by NMR spectroscopics and 6e and 6d were also characterised crystallographically. For both [CN,N'] and [CN] systems, the metallation took place regioselectively at beta-positions of the naphthyl group, (C) 2002 Elsevier Science BN. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01230-x