2-amino-N'-hydroxyethanimidamide;hydrochloride | 67015-05-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-amino-N'-hydroxyethanimidamide;hydrochloride
• CAS: 67015-05-8
• 化学式: C₂H₇N₃O*ClH
• 分子量: 125.558
• InChiKey: URYPBFHQNIISHY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tetrakis(tetrabutylammonium) octamolybdate 、 2-amino-N'-hydroxyethanimidamide;hydrochloride 以 乙腈 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Coordination chemistry of amidoximes. Molybdenum complexes of (alkyl)aminoacetamidoximes and fumaromonoamidoxime

  摘要：

  Reactions of (n-Bu4N)(2)[Mo2O7] or (n-Bu4N)(4)[alpha-Mo8O26] with RR'NCH2C(NH2)NOH (.) HCl (R = R' = H; R = H, R' = Me; R = R'= Me) inorganic solvents give complexes containing a cyclic {Mo4O12} core. The adduct [MO4O12{(Me2NHCH2C(NH2))NO}(2)]. 2(n-Bu4N)Cl has been characterized by X-ray diffraction. The complex [MO4O12{(Me2NHCH2C(NH2))NO}(2)] displays a cyclic (MoO2)(4)(mu-O)(4) ring capped by two zwitterionic amidoxime ligands through the nitrogen and oxygen atoms of the oximate group in the mu(3)-kappaN:kappa(2)O mode which is also observed for the monoamidoxime of fumaronitrile in (n-Bu4N)(2)[Mo4O12{(N=C-CH=CH-C(NH2))NO}(2)]. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01164-7